Photocatalytic CO2 reduction with varying concentrations of cat and PS

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< Photocatalytic CO2 reduction with aminoanthraquinone organic dyes
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investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Fe(DHPP)Cl

0.0005

Molecule:100932

0.0005

BIH

0.06


DMF



> 400 3174 n/a


No

Fe(DHPP)Cl

0.001

Molecule:100932

0.001

BIH

0.06


DMF



> 400 3587 n/a


No

Fe(DHPP)Cl

0.002

Molecule:100932

0.002

BIH

0.06


DMF



> 400 3817 n/a


No

Fe(DHPP)Cl

0.005

Molecule:100932

0.005

BIH

0.06


DMF



> 400 4978 n/a


No

Fe(DHPP)Cl

0.01

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4028 n/a


No

Fe(DHPP)Cl

0.0005

Molecule:100932

0.02

BIH

0.06


DMF



> 400 19158 n/a


No

Fe(DHPP)Cl

0.0006

Molecule:100932

0.02

BIH

0.06


DMF



> 400 21616 n/a


No

Fe(DHPP)Cl

0.001

Molecule:100932

0.02

BIH

0.06


DMF



> 400 17020 n/a


No

Fe(DHPP)Cl

0.002

Molecule:100932

0.02

BIH

0.06


DMF



> 400 11250 n/a


No

Fe(DHPP)Cl

0.01

Molecule:100932

0.02

BIH

0.06


DMF



> 400 3942 n/a


No

Fe(DHPP)Cl

0.02

Molecule:100932

0.02

BIH

0.06


DMF



> 400 2134 n/a


No

Fe(DHPP)Cl

0.05

Molecule:100932

0.02

BIH

0.06


DMF



> 400 891 n/a


No

Fe(DHPP)Cl

0.002

Molecule:100932

0.015

BIH

0.06


DMF



> 400 8772 n/a


No

Fe(DHPP)Cl

0.002

Molecule:100932

0.01

BIH

0.06


DMF



> 400 5593 n/a


No

Fe(DHPP)Cl

0.005

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4128 n/a


No

Fe(DHPP)Cl

0.01

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4028 n/a


No

Fe(DHPP)Cl

0.02

Molecule:100932

0.01

BIH

0.06


DMF



> 400 2325 n/a


No

Fe(DHPP)Cl

0.002

Molecule:100932

0.005

BIH

0.06


DMF



> 400 8780 n/a


No

Fe(DHPP)Cl

0.005

Molecule:100932

0.005

BIH

0.06


DMF



> 400 5258 n/a


No

Fe(DHPP)Cl

0.01

Molecule:100932

0.005

BIH

0.06


DMF



> 400 2576 n/a


No

Fe(DHPP)Cl

0.02

Molecule:100932

0.005

BIH

0.06


DMF



> 400 1539 n/a


No