Table 2

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Ru(dtBubpy)(CO)2Cl2	0.05	Molecule:100877	0.05					DMF	TEOA		5:1								436	23	20						72			290		0.58				5.2%; 0%; 18.8%; 75.9%; 0%	0.58		Yes
Ru(dtBubpy)(CO)2Cl2	0.05	Molecule:100877	0.05	BI(OH)H	0.03			DMF	TEOA		5:1								436	23	16						49			280		0.47				4.6%; 0%; 14.2%; 81.2%; 0%	0.47		Yes
[Mn(dtBubpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05					DMF	TEOA		5:1								436	12	32									85		0.48				27.4%; 0%; 0%; 72.6%; 0%	0.48		Yes
[Mn(dtBubpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05	BI(OH)H	0.03			DMF	TEOA		5:1								436	12	80									60		0.37				57.1%; 0%; 0%; 42.9%; 0%	0.37		Yes