Photoreduction of CO2
From ChemWiki
< Ir(tpy)(bpy)Cl as a Photocatalyst for CO2 Reduction under Visible-Light Irradiation
investigation
Molecular process, Photocatalytic CO2 conversion experiments"Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property."Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property."Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property."Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
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0.1 |
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5:1 | Molecule:100865 | 410 - 750 nm | 24 | 2 | 1 | 20 | 8.7%; 0%; 4.3%; 87.0%; 0% |
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Yes | ||||||||||||||||||||||||||
0.1 |
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5:1 | Molecule:100865 | 410 - 750 nm | 24 | 5 | 3 | 9 | 29.4%; 0%; 17.6%; 52.9%; 0% |
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Yes | ||||||||||||||||||||||||||
0.1 |
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5:1 | Molecule:100865 | 410 - 750 nm | 24 | 3 | 1 | 5 | 33.3%; 0%; 11.1%; 55.6%; 0% |
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Yes | ||||||||||||||||||||||||||
0.1 |
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5:1 | Molecule:100865 | 410 - 750 nm | 8 | 0 | 1 | 7 | 0%; 0%; 12.5%; 87.5%; 0% |
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Yes |