Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.02	BIH	0.1			DMF											460 (LED)	12	520						0			14						97.4%; 0%; 0%; 2.6%; 0%			Yes
[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.02	BIH	0.1			DMF				Argon atmosphere							460 (LED)	12	0						3			21						0%; 0%; 12.5%; 87.5%; 0%			Yes
[Fe(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.02	BIH	0.1			DMF											460 (LED)	12	0						139			0						n/a			Yes
[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.05	BIH	0.1			DMF											460 (LED)	12	520						0			21						96.1%; 0%; 0%; 3.9%; 0%			Yes
[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.05	BIH	0.1			DMF				Argon atmosphere							460 (LED)	12	0						0			8						n/a			Yes
[Fe(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.05	BIH	0.1			DMF											460 (LED)	12	0						0			10						n/a			Yes
[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1			DMF											460 (LED)	12	350						1			23						93.6%; 0%; 0.3%; 6.1%; 0%			Yes
[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1			DMF				Argon atmosphere							460 (LED)	12	0						54			20						0%; 0%; 73.0%; 27.0%; 0%			Yes
[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0	BIH	0.1			DMF											460 (LED)	12	0						0			24						n/a			Yes
[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.02	BIH	0.1			DMF											460 (LED)	12	0						0			8						n/a			Yes
[Fe(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.02	BIH	0.1			DMF											460 (LED)	12	1365						0			115						92.2%; 0%; 0%; 7.8%; 0%			Yes
[Fe(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.02	BIH	0.1			DMF				Argon atmosphere							460 (LED)	12	0						52			88						0%; 0%; 37.1%; 62.9%; 0%			Yes