Table 1
From ChemWiki
< Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.03 | 0.5 | 0.1 |
|
|
9:1 | 25 | 450 | 55 | 713 | 1.42 | 6.9 | 99.0%; 0%; 1.0%; 0%; 0% |
1.42 |
Yes | |||||||||||||||||||||||||
| 0.03 | 0.5 | 0.1 |
|
|
9:1 | 25 | 450 | 159 | 11 | 93.5%; 0%; 6.5%; 0%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 0.03 | 0.5 | 0.1 |
|
|
9:1 | 25 | 450 | 67 | 3.4 | 95.2%; 0%; 4.8%; 0%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 0.03 | 0.5 | 0.1 |
|
|
9:1 | 25 | 450 | n/a |
|
No | |||||||||||||||||||||||||||||
| 0.03 | 0.5 | 0.1 |
|
|
9:1 | 25 | 450 | n/a |
|
No | |||||||||||||||||||||||||||||
| 0.03 | 0.5 | 0.1 |
|
|
9:1 | 25 | 450 | 2.6 | 25.5 | 9.3%; 0%; 90.7%; 0%; 0% |
|
Yes |
