Best result and control experiments

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cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

100776

0.000025


0.4

TEOA

300


MeCN

H2O


4:1 25 450 nm (LED, 100 mW.cm^-2) 10 16896 0.47 98 368 0.01 2 97.9%; 0%; 2.1%; 0%; 0%

100

Yes

Table 1

cat cat_abb cat conc [mM] solvent A solvent B solvent-ratio [SolvA/SolvB] pH Temperature [° C] λexc [nm] include
100776 0,000025 CH3CN H2O 4:1 25 450 No