Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes/Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2: Difference between revisions
From ChemWiki
investigation
No edit summary |
Jana.alpin (talk | contribs) No edit summary |
||
| Line 2: | Line 2: | ||
|experiments={{Photocatalytic CO2 conversion | |experiments={{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.02 | |PS conc=0.02 | ||
| Line 16: | Line 16: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.02 | |PS conc=0.02 | ||
| Line 45: | Line 45: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
| Line 59: | Line 59: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
| Line 88: | Line 88: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.2 | |PS conc=0.2 | ||
| Line 102: | Line 102: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.2 | |PS conc=0.2 | ||
| Line 117: | Line 117: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0 | |PS conc=0 | ||
| Line 131: | Line 131: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.02 | |PS conc=0.02 | ||
| Line 145: | Line 145: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.02 | |PS conc=0.02 | ||
| Line 159: | Line 159: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.02 | |PS conc=0.02 | ||
Revision as of 19:01, 15 March 2025
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume [mL] | intensity [kW/m²] | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO [TOF/min] | Φ CO [%] | TON CH4 | TOF CH4 [TOF/min] | Φ CH4 [%] | TON H2 | TOF H2 [TOF/min] | Φ H2 [%] | TON HCOOH | TOF HCOOH [TOF/min] | Φ HCOOH [%] | TON MeOH | TOF MeOH [TOF/min] | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 50 | 0.02 | 0.1 |
|
|
|
460 (LED) | 12 | 520 | 0 | 14 | 97.4%; 0%; 0%; 2.6%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 50 | 0.02 | 0.1 |
|
|
|
Argon atmosphere | 460 (LED) | 12 | 0 | 3 | 21 | 0%; 0%; 12.5%; 87.5%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0 | 0.02 | 0.1 |
|
|
|
460 (LED) | 12 | 0 | 139 | 0 | n/a |
|
Yes | |||||||||||||||||||||||||||
| 50 | 0.05 | 0.1 |
|
|
|
460 (LED) | 12 | 520 | 0 | 21 | 96.1%; 0%; 0%; 3.9%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 50 | 0.05 | 0.1 |
|
|
|
Argon atmosphere | 460 (LED) | 12 | 0 | 0 | 8 | n/a |
|
Yes | ||||||||||||||||||||||||||
| 0 | 0.05 | 0.1 |
|
|
|
460 (LED) | 12 | 0 | 0 | 10 | n/a |
|
Yes | |||||||||||||||||||||||||||
| 50 | 0.2 | 0.1 |
|
|
|
460 (LED) | 12 | 350 | 1 | 23 | 93.6%; 0%; 0.3%; 6.1%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 50 | 0.2 | 0.1 |
|
|
|
Argon atmosphere | 460 (LED) | 12 | 0 | 54 | 20 | 0%; 0%; 73.0%; 27.0%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 50 | 0 | 0.1 |
|
|
|
460 (LED) | 12 | 0 | 0 | 24 | n/a |
|
Yes | |||||||||||||||||||||||||||
| 50 | 0.02 | 0.1 |
|
|
|
460 (LED) | 12 | 0 | 0 | 8 | n/a |
|
Yes | |||||||||||||||||||||||||||
| 50 | 0.02 | 0.1 |
|
|
|
460 (LED) | 12 | 1365 | 0 | 115 | 92.2%; 0%; 0%; 7.8%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 50 | 0.02 | 0.1 |
|
|
|
Argon atmosphere | 460 (LED) | 12 | 0 | 52 | 88 | 0%; 0%; 37.1%; 62.9%; 0% |
|
Yes |
