Photocatalytic CO2 reduction using a Mn complex as a catalyst/Photocatalytic CO2 reduction: conditions optimization: Difference between revisions

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investigation
Molecular process, Photocatalytic CO2 conversion experiments
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|experiments={{Photocatalytic CO2 conversion
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100752
|catalyst=Molecule:100752
|cat conc=0.05
|cat conc=50
|PS=Molecule:100659
|PS=Molecule:100659
|PS conc=0.05
|PS conc=0.05
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100752
|catalyst=Molecule:100752
|cat conc=0.05
|cat conc=50
|PS=Molecule:100659
|PS=Molecule:100659
|PS conc=0.05
|PS conc=0.05
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100752
|catalyst=Molecule:100752
|cat conc=0.05
|cat conc=50
|PS=Molecule:100659
|PS=Molecule:100659
|PS conc=0.05
|PS conc=0.05
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100752
|catalyst=Molecule:100752
|cat conc=0.05
|cat conc=50
|PS=Molecule:100659
|PS=Molecule:100659
|PS conc=0.05
|PS conc=0.05
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100752
|catalyst=Molecule:100752
|cat conc=0.05
|cat conc=50
|e-D=Molecule:100509
|e-D=Molecule:100509
|e-D conc=0.1
|e-D conc=0.1
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100752
|catalyst=Molecule:100752
|cat conc=0.05
|cat conc=50
|PS=Molecule:100659
|PS=Molecule:100659
|PS conc=0.05
|PS conc=0.05
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100752
|catalyst=Molecule:100752
|cat conc=0.05
|cat conc=50
|PS=Molecule:100659
|PS=Molecule:100659
|PS conc=0.05
|PS conc=0.05
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100752
|catalyst=Molecule:100752
|cat conc=0.05
|cat conc=50
|PS=Molecule:100680
|PS=Molecule:100680
|PS conc=0.05
|PS conc=0.05

Revision as of 18:26, 15 March 2025

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume [mL] intensity [kW/m²] pH T [°C] λexc [nm] t [h] TON CO TOF CO [TOF/min] Φ CO [%] TON CH4 TOF CH4 [TOF/min] Φ CH4 [%] TON H2 TOF H2 [TOF/min] Φ H2 [%] TON HCOOH TOF HCOOH [TOF/min] Φ HCOOH [%] TON MeOH TOF MeOH [TOF/min] Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Mn(bpy)(CO)3Br

50

[Ru(dmb)3][PF6]2

0.05

BNAH

0.1


DMF

TEOA


4:1 480 0.17 n/a


No

Mn(bpy)(CO)3Br

50

[Ru(dmb)3][PF6]2

0.05

BNAH

0.1


DMF

TEOA


4:1 480 2 n/a


Yes

Mn(bpy)(CO)3Br

50

[Ru(dmb)3][PF6]2

0.05

BNAH

0.1


DMF

TEOA


4:1 480 12 n/a


Yes

Mn(bpy)(CO)3Br

50

[Ru(dmb)3][PF6]2

0.05

BNAH

0.1


DMF

TEOA


4:1 Argon gas 480 12 n/a


Yes


[Ru(dmb)3][PF6]2

0.05

BNAH

0.1


DMF

TEOA


4:1 480 2 n/a


Yes


[Ru(dmb)3][PF6]2

0.05

BNAH

0.1


DMF

TEOA


4:1 480 12 n/a


Yes

Mn(bpy)(CO)3Br

50


BNAH

0.1


DMF

TEOA


4:1 480 12 n/a


No

Mn(bpy)(CO)3Br

50

[Ru(dmb)3][PF6]2

0.05

BNAH

0.1


DMA

TEOA


4:1 480 720 n/a


Yes


[Ru(dmb)3][PF6]2

0.05

BNAH

0.1


DMA

TEOA


4:1 480 12 n/a


Yes

Mn(bpy)(CO)3Br

50

[Ru(dmb)3][PF6]2

0.05

BNAH

0.1


MeCN

TEOA


4:1 480 12 n/a


Yes


[Ru(dmb)3][PF6]2

0.05

BNAH

0.1


MeCN

TEOA


4:1 480 12 n/a


Yes

Mn(bpy)(CO)3Br

50

Ru(bpy)3

0.05

BNAH

0.1


DMF

TEOA


4:1 480 12 n/a


Yes