Pyranopterin Related Dithiolene Molybdenum Complexes as Homogeneous Catalysts for CO2 Photoreduction/Table 1: Difference between revisions
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< Pyranopterin Related Dithiolene Molybdenum Complexes as Homogeneous Catalysts for CO2 Photoreduction
investigation
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|experiments={{Photocatalytic CO2 conversion | |experiments={{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100662 | |catalyst=Molecule:100662 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.5 | |PS conc=0.5 | ||
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}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100660 | |catalyst=Molecule:100660 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.5 | |PS conc=0.5 | ||
| Line 36: | Line 36: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100661 | |catalyst=Molecule:100661 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.5 | |PS conc=0.5 | ||
Revision as of 17:43, 14 March 2025
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume [mL] | intensity [kW/m²] | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO [TOF/min] | Φ CO [%] | TON CH4 | TOF CH4 [TOF/min] | Φ CH4 [%] | TON H2 | TOF H2 [TOF/min] | Φ H2 [%] | TON HCOOH | TOF HCOOH [TOF/min] | Φ HCOOH [%] | TON MeOH | TOF MeOH [TOF/min] | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 50 | 0.5 | 0.1 |
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|
5:1 | 20 | 400 | 15 | n/a |
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Yes | |||||||||||||||||||||||||||||
| 50 | 0.5 | 0.1 |
|
|
5:1 | 20 | 400 | 15 | n/a |
|
Yes | |||||||||||||||||||||||||||||
| 50 | 0.5 | 0.1 |
|
|
5:1 | 20 | 400 | 15 | n/a |
|
Yes |
