Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer/Table 1

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume [mL]	intensity [kW/m²]	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON CH4	TOF CH4 [TOF/min]	Φ CH4 [%]	TON H2	TOF H2 [TOF/min]	Φ H2 [%]	TON HCOOH	TOF HCOOH [TOF/min]	Φ HCOOH [%]	TON MeOH	TOF MeOH [TOF/min]	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Mn(bpy)(CO)3Br	2000	ZnTPP	0.5	TEA	0.1			MeCN	H2O		20:1								xenon lamp	3	119									19						86.2%; 0%; 0%; 13.8%; 0%			Yes
Mn(bpy)(CO)3Br	1500	ZnTPP	0.5	TEA	0.1			MeCN	H2O		20:1								xenon lamp	3	97									18						84.3%; 0%; 0%; 15.7%; 0%			Yes
Mn(bpy)(CO)3Br	500	ZnTPP	0.25	TEA	0.1			MeCN	H2O		20:1								xenon lamp	3	64									16						80.0%; 0%; 0%; 20.0%; 0%			Yes
Mn(bpy)(CO)3Br	500	ZnTPP	0.5	TEA	0.1			MeCN	H2O		20:1								xenon lamp	3	12									10						54.5%; 0%; 0%; 45.5%; 0%			Yes
Mn(bpy)(CO)3Br	500	ZnTPP	1	TEA	0.1			MeCN	H2O		20:1								xenon lamp	3	8									6						57.1%; 0%; 0%; 42.9%; 0%			Yes
Mn(bpy)(CO)3Br	500			TEA	0.1			MeCN	H2O		20:1								xenon lamp	3	2									1						66.7%; 0%; 0%; 33.3%; 0%			Yes
		ZnTPP	0.5	TEA	0.1			MeCN	H2O		20:1								xenon lamp	3																n/a			No