A molecular noble metal-free system for efficient visible light-driven reduction of CO2 to CO/experiments: Difference between revisions

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investigation
Molecular process, Photocatalytic CO2 conversion experiments
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|e-D=Molecule:100508
|e-D=Molecule:100508
|e-D conc=0.1
|e-D conc=0.1
|H-D=Molecule:100618
|H-D conc=5%
|solvent A=Molecule:100529
|feedstock gas=CO2
|λexc=460
|irr time=15
|TON CO=0
|TON H2=0
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:101019
|cat conc=50
|PS=Molecule:100499
|PS conc=0
|e-D=Molecule:100508
|e-D conc=0
|H-D=Molecule:100618
|H-D=Molecule:100618
|H-D conc=5%
|H-D conc=5%

Latest revision as of 10:18, 11 February 2025

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume [mL] intensity [kW/m²] pH T [°C] λexc [nm] t [h] TON CO TOF CO [TOF/min] Φ CO [%] TON CH4 TOF CH4 [TOF/min] Φ CH4 [%] TON H2 TOF H2 [TOF/min] Φ H2 [%] TON HCOOH TOF HCOOH [TOF/min] Φ HCOOH [%] TON MeOH TOF MeOH [TOF/min] Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:101019

50

purpurin

0.05

BIH

0.1

TFE

5%

DMF



CO2 460 15 544 4 99.3%; 0%; 0.7%; 0%; 0%


No "%" is not declared as a valid unit of measurement for this property.

Molecule:101019

0

purpurin

0.05

BIH

0.1

TFE

5%

DMF



CO2 460 15 0 21 n/a


No "%" is not declared as a valid unit of measurement for this property.

Molecule:101019

50

purpurin

0

BIH

0.1

TFE

5%

DMF



CO2 460 15 0 0 n/a


No "%" is not declared as a valid unit of measurement for this property.

Molecule:101019

50

purpurin

0

BIH

0

TFE

5%

DMF



CO2 460 15 0 0 n/a


No "%" is not declared as a valid unit of measurement for this property.