A molecular noble metal-free system for efficient visible light-driven reduction of CO2 to CO/experiments: Difference between revisions

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investigation
Molecular process, Photocatalytic CO2 conversion experiments
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{{Photocatalytic_CO2_conversion_experiments|experiments={{Photocatalytic_CO2_conversion
{{Photocatalytic CO2 conversion experiments
|catalyst=Molecule:
|experiments={{Photocatalytic CO2 conversion
|cat conc=2
|catalyst=Molecule:101019
|PS=Molecule:100843
|cat conc=50
|PS conc=0.2
|PS=Molecule:100499
|PS conc=0.05
|e-D=Molecule:100508
|e-D=Molecule:100508
|e-D conc=0.1
|e-D conc=0.1
|H-D=Molecule:100617
|H-D=Molecule:100618
|H-D conc=1
|H-D conc=5%
|solvent A=Molecule:100530
|solvent A=Molecule:100529
|feedstock gas=CO2
|feedstock gas=CO2
|irr time=1.5
|λexc=460
|TON CO=18502
|irr time=15
|TON H2=141
|TON CO=544
|details=in 5 mL solvent, 90-120 min
|TON H2=4
|include=false
|include=No
}}{{Photocatalytic_CO2_conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:
|catalyst=Molecule:
|cat conc=0.2
|cat conc=0.2
Line 29: Line 30:
|TON CO=28712
|TON CO=28712
|TON H2=6527
|TON H2=6527
|include=No
|details=in 5 mL solvent, 90-120 min
|details=in 5 mL solvent, 90-120 min
|include=false
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic_CO2_conversion
|catalyst=Molecule:
|catalyst=Molecule:
|cat conc=2
|cat conc=2
Line 45: Line 46:
|TON CO=12749
|TON CO=12749
|TON H2=163
|TON H2=163
|include=No
|details=in 5 mL solvent, 90-120 min
|details=in 5 mL solvent, 90-120 min
|include=false
}}
}}
}}
}}

Revision as of 10:11, 11 February 2025

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume [mL] intensity [kW/m²] pH T [°C] λexc [nm] t [h] TON CO TOF CO [TOF/min] Φ CO [%] TON CH4 TOF CH4 [TOF/min] Φ CH4 [%] TON H2 TOF H2 [TOF/min] Φ H2 [%] TON HCOOH TOF HCOOH [TOF/min] Φ HCOOH [%] TON MeOH TOF MeOH [TOF/min] Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:101019

50

purpurin

0.05

BIH

0.1

TFE

5%

DMF



CO2 460 15 544 4 99.3%; 0%; 0.7%; 0%; 0%


No "%" is not declared as a valid unit of measurement for this property.

[[Molecule: |The page type input value "Molecule:" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.]]

0.2

Molecule:100971

0.2

BIH

0.1

PhOH

1

MeCN



CO2 1.5 28712 6527 81.5%; 0%; 18.5%; 0%; 0%


in 5 mL solvent, 90-120 min No Property "Catalyst" (as page type) with input value "Molecule:" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.

[[Molecule: |The page type input value "Molecule:" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.]]

2

Molecule:100971

0.2

BIH

0.1

PhOH

1

MeCN



CO2 1.5 12749 163 98.7%; 0%; 1.3%; 0%; 0%


in 5 mL solvent, 90-120 min No Property "Catalyst" (as page type) with input value "Molecule:" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.