Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst/Photocatalytic reduction of CO: Difference between revisions
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< Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
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|experiments={{Photocatalytic CO2 conversion | |experiments={{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
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}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
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}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
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}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
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}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
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}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
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}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
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}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
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}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
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}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
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|PS=Molecule:100493 | |PS=Molecule:100493 | ||
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}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
Latest revision as of 15:31, 17 January 2025
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume [mL] | intensity [kW/m²] | pH | T [] | λexc [nm] | t [h] | TON CO | TOF CO [TOF/min] | Φ CO [%] | TON CH4 | TOF CH4 [TOF/min] | Φ CH4 [%] | TON H2 | TOF H2 [TOF/min] | Φ H2 [%] | TON HCOOH | TOF HCOOH [TOF/min] | Φ HCOOH [%] | TON MeOH | TOF MeOH [TOF/min] | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 10 | 1 | 0.1 |
|
|
|
CO | Visible light (>435) | 47 | 10 | 21 | 0%; 32.3%; 67.7%; 0%; 0% |
|
No | ||||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
TFE | 0.1 | CO | Visible light (>435) | 47 | 45 | 7 | 0%; 86.5%; 13.5%; 0%; 0% |
|
No | ||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
TFE | 0.1 | CO | Visible light (>435) | 47 | 21 | 9 | 0%; 70.0%; 30.0%; 0%; 0% |
|
No | ||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
TFE | 0.1 | CO | Visible light (>435) | 47 | 39 | 7 | 0%; 84.8%; 15.2%; 0%; 0% |
|
No | ||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
TFE | 0.1 | CO | Visible light (>435) | 47 | 46 | 8 | 0%; 85.2%; 14.8%; 0%; 0% |
|
No | ||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
TFE | 0.1 | CO | Visible light (>435) | 102 | 80 | 14 | 0%; 85.1%; 14.9%; 0%; 0% |
|
No | ||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
TFE | 0.25 | CO | Visible light (>435) | 47 | 27 | 17 | 0%; 61.4%; 38.6%; 0%; 0% |
|
No | ||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
TFE | 0.5 | CO | Visible light (>435) | 47 | 17 | 37 | 0%; 31.5%; 68.5%; 0%; 0% |
|
No | ||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
water | 0.1 | CO | Visible light (>435) | 47 | 10 | 5 | 0%; 66.7%; 33.3%; 0%; 0% |
|
No | ||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
water | 0.5 | CO | Visible light (>435) | 47 | 12 | 6 | 0%; 66.7%; 33.3%; 0%; 0% |
|
No | ||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
PhOH | 0.1 | CO | Visible light (>435) | 47 | 26 | 44 | 0%; 37.1%; 62.9%; 0%; 0% |
|
No |
