Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4/Results for different electron donors and proton donors: Difference between revisions

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investigation
Molecular process, Photocatalytic CO2 conversion experiments
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{{Photocatalytic CO2 conversion experiments
{{Cyclic_Voltammetry_experiments|experiments={{Cyclic_Voltammetry
|experiments={{Photocatalytic CO2 conversion
|=Molecule:100831
|catalyst=Molecule:100829
|=0.002
|cat conc=2
|=Molecule:100843
|PS=Molecule:100843
|=0.1
|PS conc=0.1
|=Molecule:100508
|e-D=Molecule:100508
|=0.01
|e-D conc=0.01
|solv=Molecule:100530
|solvent A=Molecule:100530
|=TEA, H2O
|additives=TEA
|=CO2
|feedstock gas=CO2
|=solar spectrum
|λexc=solar spectrum
|=72
|irr time=72
|=8000
|TON CO=108000
|=5000
|TON CH4=4000
|=34000
|TON H2=278000
|include=true
}}{{Cyclic_Voltammetry
|=Molecule:100829
|=0.002
|=Molecule:100843
|=0.1
|=Molecule:100508
|=0.01
|solv=Molecule:100530
|=TEA 5% (v/v), H2O 2% (v/v)
|=CO
|=solar spectrum
|=72
|=10000
|=58000
|include=true
}}{{Cyclic_Voltammetry
|=Molecule:100831
|=0.002
|=Molecule:100843
|=0.1
|=Molecule:100505
|solv=Molecule:100530
|=CO2
|=solar spectrum
|=72
|=5000
|=1000
|=15000
|include=true
}}{{Cyclic_Voltammetry
|=Molecule:100829
|=0.002
|=Molecule:100843
|=0.1
|=Molecule:100508
|=0.01
|solv=Molecule:100530
|=TEA
|=CO2
|=solar spectrum
|=72
|=108000
|=4000
|=278000
|details=test
|details=test
|include=Yes
|include=true
}}{{Photocatalytic CO2 conversion
}}{{Cyclic_Voltammetry
|catalyst=Molecule:100829
|=Molecule:100829
|cat conc=2
|=0.002
|PS=Molecule:100843
|=Molecule:100843
|PS conc=0.1
|=0.1
|e-D=Molecule:100508
|=Molecule:100508
|e-D conc=0.01
|=0.01
|solvent A=Molecule:100530
|solv=Molecule:100530
|additives=TEA, H2O
|=TEA, H2O
|feedstock gas=CO2
|=CO2
|λexc=solar spectrum
|=solar spectrum
|irr time=72
|=72
|TON CO=31000
|=31000
|TON H2=320000
|=320000
|include=Yes
|include=true
}}{{Photocatalytic CO2 conversion
}}{{Cyclic_Voltammetry
|catalyst=Molecule:100829
|=Molecule:100830
|cat conc=2
|=0.002
|PS=Molecule:100843
|=Molecule:100843
|PS conc=0.1
|=0.1
|e-D=Molecule:100505
|=Molecule:100508
|solvent A=Molecule:100530
|=0.01
|feedstock gas=CO2
|solv=Molecule:100530
|λexc=solar spectrum
|=TEA, H2O
|irr time=72
|=CO2
|TON CO=130000
|=solar spectrum
|TON CH4=29000
|=72
|TON H2=4900000
|=175000
|include=Yes
|=19000
}}{{Photocatalytic CO2 conversion
|=29000
|catalyst=Molecule:100830
|include=true
|cat conc=2
}}{{Cyclic_Voltammetry
|PS=Molecule:100843
|=Molecule:100830
|PS conc=0.1
|=0.002
|e-D=Molecule:100508
|=Molecule:100843
|e-D conc=0.01
|=0.1
|solvent A=Molecule:100530
|=Molecule:100505
|additives=TEA
|solv=Molecule:100530
|feedstock gas=CO2
|=CO2
|λexc=solar spectrum
|=solar spectrum
|irr time=72
|=72
|TON CO=310000
|=9000
|TON H2=33000
|=36000
|include=Yes
|include=true
}}{{Photocatalytic CO2 conversion
}}{{Cyclic_Voltammetry
|catalyst=Molecule:100830
|=Molecule:100829
|cat conc=2
|=0.002
|PS=Molecule:100843
|=Molecule:100843
|PS conc=0.1
|=0.1
|e-D=Molecule:100508
|=Molecule:100505
|e-D conc=0.01
|solv=Molecule:100530
|solvent A=Molecule:100530
|=CO2
|additives=TEA, H2O
|=solar spectrum
|feedstock gas=CO2
|=72
|λexc=solar spectrum
|=130000
|irr time=72
|=29000
|TON CO=175000
|=4900000
|TON CH4=19000
|include=true
|TON H2=29000
}}{{Cyclic_Voltammetry
|include=Yes
|=Molecule:100831
}}{{Photocatalytic CO2 conversion
|=0.002
|catalyst=Molecule:100830
|=Molecule:100843
|cat conc=2
|=0.1
|PS=Molecule:100843
|=Molecule:100508
|PS conc=0.1
|=0.01
|e-D=Molecule:100505
|solv=Molecule:100530
|solvent A=Molecule:100530
|=TEA
|feedstock gas=CO2
|=CO2
|λexc=solar spectrum
|=solar spectrum
|irr time=72
|=72
|TON CO=9000
|=76000
|TON H2=36000
|=17000
|include=Yes
|include=true
}}{{Photocatalytic CO2 conversion
}}{{Cyclic_Voltammetry
|catalyst=Molecule:100831
|=Molecule:100829
|cat conc=2
|=0.002
|PS=Molecule:100843
|=Molecule:100843
|PS conc=0.1
|=0.1
|e-D=Molecule:100508
|=Molecule:100508
|e-D conc=0.01
|=0.01
|solvent A=Molecule:100530
|solv=Molecule:100530
|additives=TEA
|=TEA 5% (v/v), H2O 2% (v/v)
|feedstock gas=CO2
|=solar spectrum
|λexc=solar spectrum
|=72
|irr time=72
|=570000
|TON CO=76000
|details=Atmosphere of 1:1 CO/H2
|TON H2=17000
|include=true
|include=Yes
}}{{Cyclic_Voltammetry
}}{{Photocatalytic CO2 conversion
|=Molecule:100829
|catalyst=Molecule:100831
|=0.002
|cat conc=2
|=Molecule:100843
|PS=Molecule:100843
|=0.1
|PS conc=0.1
|=Molecule:100508
|e-D=Molecule:100508
|=0.01
|e-D conc=0.01
|solv=Molecule:100530
|solvent A=Molecule:100530
|=TEA, H2O
|additives=TEA, H2O
|=solar spectrum
|feedstock gas=CO2
|=72
|λexc=solar spectrum
|=51000
|irr time=72
|=12000
|TON CO=8000
|TON CH4=5000
|TON H2=34000
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100831
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100505
|solvent A=Molecule:100530
|feedstock gas=CO2
|λexc=solar spectrum
|irr time=72
|TON CO=5000
|TON CH4=1000
|TON H2=15000
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100829
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|additives=TEA, H2O
|λexc=solar spectrum
|irr time=72
|TON CO=51000
|TON CH4=12000
|details=Atmosphere of 1:1 CO2/H2
|details=Atmosphere of 1:1 CO2/H2
|include=Yes
|include=true
}}{{Photocatalytic CO2 conversion
}}{{Cyclic_Voltammetry
|catalyst=Molecule:100829
|=Molecule:100830
|cat conc=2
|=0.002
|PS=Molecule:100843
|=Molecule:100843
|PS conc=0.1
|=0.1
|e-D=Molecule:100508
|=Molecule:100508
|e-D conc=0.01
|=0.01
|solvent A=Molecule:100530
|solv=Molecule:100530
|additives=TEA 5% (v/v), H2O 2% (v/v)
|=TEA
|feedstock gas=CO
|=CO2
|λexc=solar spectrum
|=solar spectrum
|irr time=72
|=72
|TON CH4=10000
|=310000
|TON H2=58000
|=33000
|include=Yes
|include=true
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100829
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|additives=TEA 5% (v/v), H2O 2% (v/v)
|λexc=solar spectrum
|irr time=72
|TON CH4=570000
|details=Atmosphere of 1:1 CO/H2
|include=Yes
}}
}}
}}
}}

Revision as of 17:45, 16 December 2024

analyte anl conc [M] reduction potential ERed [V] oxidation potential EOx [V] *E0,0 [V] *ERed [V] *EOx [V] solvent solvent vol [ml] electrolyte electrolyte purity el conc [M] int ref comp scan rate [mV/s] scan number potential window scan dir gas T [] condition [nm] WE WE SA [mm²] CE RE Details include


MeCN



true


MeCN



true


MeCN



true


MeCN



test true


MeCN



true


MeCN



true


MeCN



true


MeCN



true


MeCN



true


MeCN



Atmosphere of 1:1 CO/H2 true


MeCN



Atmosphere of 1:1 CO2/H2 true


MeCN



true
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