Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction/CO2+ results from SI

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Molecule:100969	2	Ru(bpy)3	0.2	BIH	0.1	PhOH	1	MeCN						CO2						90		2.8333333333333						7.73								n/a		in 5 mL solvent
Molecule:100969	2	Molecule:100971	0.2	BIH	0.1	PhOH	1	MeCN						CO2						90		2.0333333333333						8.53								n/a		in 5 mL solvent
Molecule:100969	2	Ir(ppy)3	0.2	BIH	0.05	PhOH	1	MeCN						CO2						90		4.2666666666667						10.92								n/a		in 5 mL solvent
Molecule:100969	2	Molecule:100971	0.2	BIH	0.05	PhOH	1	MeCN						CO2						90		10.783333333333						2.2								n/a		in 5 mL solvent
Molecule:100969	2	Ru(bpy)3	0.2	BIH	0.05	PhOH	1	MeCN						CO2						90		6.2666666666667						3.15								n/a		in 5 mL solvent
Molecule:100969	2	Molecule:100971	0.2	TEA	0.05	PhOH	1	MeCN						CO2						90		2						0.133								n/a		in 5 mL solvent
Molecule:100969	2	Molecule:100971	0.2	TEA	0.05	PhOH	0.5	MeCN						CO2						90		0.21666666666667						0.97								n/a		in 5 mL solvent
Molecule:100969	2	Molecule:100971	0.2	TEA	0.05	Molecule:100972	0.1	MeCN						CO2						90		0.23333333333333						1.2								n/a		in 5 mL solvent
Molecule:100969	2	Molecule:100971	0.2	TEA	0.05	TFE	0.1	MeCN						CO2						90		0.3						0.483								n/a		in 5 mL solvent