Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy/photocatalytic CO2 conversion under different conditions: Difference between revisions
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< Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy
investigation
Molecular process, Photocatalytic CO2 conversion experiments (Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |include=No }} }}") |
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{{Photocatalytic CO2 conversion experiments | {{Photocatalytic CO2 conversion experiments | ||
|experiments={{Photocatalytic CO2 conversion | |experiments={{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100951 | |||
|cat conc=2.5 | |||
|PS=Molecule:100952 | |||
|PS conc=0.005 | |||
|e-D=Molecule:100861 | |||
|e-D conc=0.05 | |||
|solvent A=Molecule:100530 | |||
|solvent B=Molecule:100616 | |||
|solvent-ratio=4:1 | |||
|λexc=400 | |||
|irr time=4 | |||
|TON CO=2750 | |||
|TOF CO=687 | |||
|details=TON and TOF calc. for PS | |||
|include=No | |include=No | ||
}} | }} | ||
}} | }} |
Revision as of 11:44, 17 May 2024
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
2.5 | 0.005 | 0.05 |
|
|
4:1 | 400 | 4 | 2750 | 687 | n/a |
|
TON and TOF calc. for PS | No |