Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy/photocatalytic CO2 conversion under different conditions: Difference between revisions

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< Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy
investigation
Molecular process, Photocatalytic CO2 conversion experiments
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{{Photocatalytic CO2 conversion experiments
{{Photocatalytic CO2 conversion experiments
|experiments={{Photocatalytic CO2 conversion
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100951
|cat conc=2.5
|PS=Molecule:100952
|PS conc=0.005
|e-D=Molecule:100861
|e-D conc=0.05
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=4:1
|λexc=400
|irr time=4
|TON CO=2750
|TOF CO=687
|details=TON and TOF calc. for PS
|include=No
|include=No
}}
}}
}}
}}

Revision as of 11:44, 17 May 2024

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100951

2.5

Molecule:100952

0.005

Molecule:100861

0.05


MeCN

H2O


4:1 400 4 2750 687 n/a


TON and TOF calc. for PS No