Photocatalytic Reduction of CO2 by Highly Efficient Homogeneous FeII Catalyst based on 2,6-Bis(1’,2’,3’-triazolyl-methyl)pyridine. Comparison with Analogues./CO2 reduction experiments testing different catalysts: Difference between revisions

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|TON CO=7.8
|TON CO=7.8
|TON H2=2
|TON H2=2
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100944
|cat conc=0.1
|PS=Molecule:100940
|PS conc=1.0
|e-D=Molecule:100508
|e-D conc=0.02
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|λexc=420
|irr time=4
|TON CO=1.1
|TON H2=7.4
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100946
|cat conc=0.1
|PS=Molecule:100940
|PS conc=1.0
|e-D=Molecule:100508
|e-D conc=0.02
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|λexc=420
|irr time=4
|TON CO=0.7
|TON H2=4.9
|include=No
|include=No
}}
}}
}}
}}

Revision as of 12:56, 16 May 2024

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100942

0.1

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 420 4 7.8 2 79.6%; 0%; 20.4%; 0%; 0%


No

Molecule:100944

0.1

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 420 4 1.1 7.4 12.9%; 0%; 87.1%; 0%; 0%


No

Molecule:100946

0.1

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 420 4 0.7 4.9 12.5%; 0%; 87.5%; 0%; 0%


No