Photocatalytic Reduction of CO2 by Highly Efficient Homogeneous FeII Catalyst based on 2,6-Bis(1’,2’,3’-triazolyl-methyl)pyridine. Comparison with Analogues./CO2 reduction experiments testing different catalysts: Difference between revisions

Revision as of 12:55, 16 May 2024

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Molecule:100942	0.1	Molecule:100940	1.0	BIH	0.02			MeCN	TEOA		5:1			CO2					420	4	7.8						2									79.6%; 0%; 20.4%; 0%; 0%			No

@@ Line 1: / Line 1: @@
 {{Photocatalytic CO2 conversion experiments
 |experiments={{Photocatalytic CO2 conversion
+|catalyst=Molecule:100942
+|cat conc=0.1
+|PS=Molecule:100940
+|PS conc=1.0
 |e-D=Molecule:100508
 |e-D conc=0.02
 |solvent A=Molecule:100530
 |solvent B=Molecule:100507
+|solvent-ratio=5:1
+|feedstock gas=CO2
 |λexc=420
 |irr time=4
-|TON CO=1.1
+|TON CO=7.8
-|TON H2=7.4
+|TON H2=2
 |include=No
 }}
 }}