Water-Assisted Highly Efficient Photocatalytic Reduction of CO2 to CO with Noble Metal-Free Bis(terpyridine)iron(II) Complexes and an Organic Photosensitizer/photocatalytic CO2 conversion

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Molecule:100949	0.01	4CzIPN	0.05	TEA	0.28			DMF	H2O		3:2			CO2					420-650	2	6320	127														n/a			Yes
Molecule:100948	0.01	4CzIPN	0.05	TEA	0.28			DMF	H2O		3:2			CO2					420-650	2	2780															n/a			No
Molecule:100947	0.01	4CzIPN	0.05	TEA	0.28			DMF	H2O		3:2			CO2					420-650	2	4500															n/a			No
Molecule:100949	0.01	Ru(bpy)3	0.05	TEA	0.28			DMF	H2O		3:2			CO2					420-650	2	19															n/a			No
Molecule:100949	0.01	Ru(bpy)3	0.05	TEA	0.28			MeCN	H2O		3:2			CO2					420-650	2	992															n/a			No