Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore/Photocatalytic CO2 reduction: best results: Difference between revisions

Revision as of 14:52, 15 February 2024

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON H2	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	include
Fe(DHPP)Cl	0.0002		0.1	BIH	0.01	DMF	>400	7	88	45	100	0	n/a	100	Yes
Fe(DHPP)Cl	0.0002	[Cu(PP)2][TBA]2	0.1	BIH	0.01	DMF	>400	7	4779	1356		270	94.7%; 0%; 5.3%; 0%; 0%		Yes
Fe(DHPP)Cl	0.0002	[Cu(PP)2][TBA]2	0.1	BIH	0.1	DMF	>400	23	16109	7650		843	95.0%; 0%; 5.0%; 0%; 0%		Yes
Fe(DHPP)Cl	0	[Cu(PP)2][TBA]2	0.1	BIH	0.1	DMF	>400	1	4.4	4.3			n/a		Yes

@@ Line 1: / Line 1: @@
 {{Photocatalytic CO2 conversion experiments
 |experiments={{Photocatalytic CO2 conversion
+|catalyst=Molecule:100671
+|cat conc=0.0002
+|PS conc=0.1
+|e-D=Molecule:100508
+|e-D conc=0.01
+|solvent A=Molecule:100529
+|λexc=>400
+|irr time=7
+|TON CO=88
+|TOF CO=45
+|Φ CO=100
+|TON H2=0
+|include=Yes
+}}{{Photocatalytic CO2 conversion
 |catalyst=Molecule:100671
 |cat conc=0.0002
@@ Line 30: / Line 44: @@
 }}{{Photocatalytic CO2 conversion
 |catalyst=Molecule:100671
-|cat conc=0.0002
+|cat conc=0
+|PS=Molecule:100771
+|PS conc=0.1
 |e-D=Molecule:100508
 |e-D conc=0.1