A Dinuclear Cobalt Cryptate as a Homogeneous Photocatalyst for Highly Selective and Efficient Visible-Light Driven CO2 Reduction to CO in CH3CN-H2O Solution/Best result and control experiments: Difference between revisions
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m Victor.larignon moved page Best result and control experiments to Best result and control experiments: first name was not specific enough |
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|solvent B=Molecule:100616 | |solvent B=Molecule:100616 | ||
|solvent-ratio=4:1 | |solvent-ratio=4:1 | ||
|feedstock gas=Molecule:100865 | |||
|Temperature=25 | |Temperature=25 | ||
|λexc=450 nm (LED, 100 mW.cm^-2) | |λexc=450 nm (LED, 100 mW.cm^-2) | ||
| Line 31: | Line 32: | ||
|solvent-ratio=4:1 | |solvent-ratio=4:1 | ||
|additives=CO2/Ar (10:90) atmosphere | |additives=CO2/Ar (10:90) atmosphere | ||
|feedstock gas=Molecule:100865 | |||
|Temperature=25 | |Temperature=25 | ||
|λexc=450 nm (LED, 100 mW.cm^-2) | |λexc=450 nm (LED, 100 mW.cm^-2) | ||
| Line 49: | Line 51: | ||
|solvent B=Molecule:100616 | |solvent B=Molecule:100616 | ||
|solvent-ratio=4:1 | |solvent-ratio=4:1 | ||
|feedstock gas=Molecule:100865 | |||
|Temperature=25 | |Temperature=25 | ||
|λexc=450 nm (LED, 100 mW.cm^-2) | |λexc=450 nm (LED, 100 mW.cm^-2) | ||
| Line 61: | Line 64: | ||
|solvent B=Molecule:100616 | |solvent B=Molecule:100616 | ||
|solvent-ratio=4:1 | |solvent-ratio=4:1 | ||
|feedstock gas=Molecule:100865 | |||
|Temperature=25 | |Temperature=25 | ||
|λexc=450 nm (LED, 100 mW.cm^-2) | |λexc=450 nm (LED, 100 mW.cm^-2) | ||
| Line 73: | Line 77: | ||
|solvent B=Molecule:100616 | |solvent B=Molecule:100616 | ||
|solvent-ratio=4:1 | |solvent-ratio=4:1 | ||
|feedstock gas=Molecule:100865 | |||
|Temperature=25 | |Temperature=25 | ||
|λexc=450 nm (LED, 100 mW.cm^-2) | |λexc=450 nm (LED, 100 mW.cm^-2) | ||
| Line 87: | Line 92: | ||
|solvent B=Molecule:100616 | |solvent B=Molecule:100616 | ||
|solvent-ratio=4:1 | |solvent-ratio=4:1 | ||
|feedstock gas=Molecule:100865 | |||
|Temperature=25 | |Temperature=25 | ||
|irr time=10 | |irr time=10 | ||
| Line 101: | Line 107: | ||
|solvent-ratio=4:1 | |solvent-ratio=4:1 | ||
|additives=Argon atmosphere | |additives=Argon atmosphere | ||
|feedstock gas=Molecule:100865 | |||
|Temperature=25 | |Temperature=25 | ||
|λexc=450 nm (LED, 100 mW.cm^-2) | |λexc=450 nm (LED, 100 mW.cm^-2) | ||
Revision as of 17:47, 14 February 2024
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume [mL] | intensity [kW/m²] | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO [TOF/min] | Φ CO [%] | TON CH4 | TOF CH4 [TOF/min] | Φ CH4 [%] | TON H2 | TOF H2 [TOF/min] | Φ H2 [%] | TON HCOOH | TOF HCOOH [TOF/min] | Φ HCOOH [%] | TON MeOH | TOF MeOH [TOF/min] | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.000025 | 0.4 | 300 |
|
|
4:1 | Molecule:100865 | 25 | 450 nm (LED, 100 mW.cm^-2) | 10 | 16896 | 0.47 | 98 | 368 | 0.01 | 2 | 97.9%; 0%; 2.1%; 0%; 0% |
100 |
Yes | "Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property. | |||||||||||||||||||||
| 0.0005 | 0.4 | 300 |
|
|
4:1 | CO2/Ar (10:90) atmosphere | Molecule:100865 | 25 | 450 nm (LED, 100 mW.cm^-2) | 10 | 684 | 0.019 | 92 | 56 | 0.0016 | 8 | 92.4%; 0%; 7.6%; 0%; 0% |
100 |
No | "Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property. | ||||||||||||||||||||
|
|
0.4 | 300 |
|
|
4:1 | Molecule:100865 | 25 | 450 nm (LED, 100 mW.cm^-2) | 10 | n/a |
|
Yes | "Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property. | |||||||||||||||||||||||||||
| 0.000025 |
|
300 |
|
|
4:1 | Molecule:100865 | 25 | 450 nm (LED, 100 mW.cm^-2) | 10 | n/a |
|
Yes | "Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property. | |||||||||||||||||||||||||||
| 0.000025 | 0.4 |
|
|
|
4:1 | Molecule:100865 | 25 | 450 nm (LED, 100 mW.cm^-2) | 10 | n/a |
|
Yes | "Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property. | |||||||||||||||||||||||||||
| 0.000025 | 0.4 | 300 |
|
|
4:1 | Molecule:100865 | 25 | 10 | n/a |
|
Yes | "Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property. | ||||||||||||||||||||||||||||
| 0.000025 | 0.4 | 300 |
|
|
4:1 | Argon atmosphere | Molecule:100865 | 25 | 450 nm (LED, 100 mW.cm^-2) | 10 | n/a |
|
Yes | "Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property. |
