Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst/Photocatalytic reduction of CO2: Difference between revisions

From ChemWiki
< Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst
investigation
Molecular process, Photocatalytic CO2 conversion experiments
← Older editNewer edit →
VisualWikitext
No edit summary
No edit summary
Line 1: Line 1:
{{Photocatalytic CO2 conversion experiments
{{Photocatalytic CO2 conversion experiments
|experiments={{Photocatalytic CO2 conversion
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 15: Line 15:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 31: Line 31:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 47: Line 47:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 60: Line 60:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 75: Line 75:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 90: Line 90:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 105: Line 105:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 120: Line 120:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 135: Line 135:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 150: Line 150:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 165: Line 165:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 180: Line 180:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493
Line 195: Line 195:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100669
|catalyst=Molecule:100826
|cat conc=0.01
|cat conc=0.01
|PS=Molecule:100493
|PS=Molecule:100493

Revision as of 14:32, 28 November 2023

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume [mL] intensity [kW/m²] pH T [°C] λexc [nm] t [h] TON CO TOF CO [TOF/min] Φ CO [%] TON CH4 TOF CH4 [TOF/min] Φ CH4 [%] TON H2 TOF H2 [TOF/min] Φ H2 [%] TON HCOOH TOF HCOOH [TOF/min] Φ HCOOH [%] TON MeOH TOF MeOH [TOF/min] Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEA

0.1


DMF



> 435 47 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEA

0.1


DMF



TFE 0.1 > 435 47 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEA

0.1


DMF



TFE 0.1 > 435 102 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEA

0.1


DMF



> 435 47 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEA

0.1


DMF



TFE 0.1 > 435 47 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEOA

0.1


DMF



TFE 0.1 > 435 47 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

DIPEA

0.1


DMF



TFE 0.1 > 435 47 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

BIH

0.1


DMF



TFE 0.1 > 435 47 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEA

0.1


DMF



TFE 0.1 > 435 102 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEA

0.1


DMF



TFE 0.25 > 435 47 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEA

0.1


DMF



TFE 0.5 > 435 47 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEA

0.1


DMF



H2O 0.1 > 435 47 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEA

0.1


DMF



H2O 0.5 > 435 47 n/a


Yes

Fe(pTMAPP)Cl5

0.01

Molecule:100493

1

TEA

0.1


DMF



PhOH 0.1 > 435 47 n/a


Yes
Retrieved from "https://chemwiki.scc.kit.edu/main/mediawiki/index.php?title=Visible-Light-Driven_Conversion_of_CO2_to_CH4_with_an_Organic_Sensitizer_and_an_Iron_Porphyrin_Catalyst/Photocatalytic_reduction_of_CO2&oldid=4559"
Powered by MediaWiki
Powered by Semantic MediaWiki