Carbon dioxide reduction via light activation of a ruthenium–Ni(cyclam) complex/Photoreduction of CO2 result: Difference between revisions

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< Carbon dioxide reduction via light activation of a ruthenium–Ni(cyclam) complex
investigation
Molecular process, Photocatalytic CO2 conversion experiments
(Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100630 |cat conc=0.03 |solvent A=Molecule:100616 |additives=ascorba...")
 
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{{Photocatalytic CO2 conversion experiments
{{Photocatalytic CO2 conversion experiments
|experiments={{Photocatalytic CO2 conversion
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100630
|catalyst=Molecule:100813
|cat conc=0.03
|cat conc=0.03
|solvent A=Molecule:100616
|solvent A=Molecule:100616

Revision as of 18:40, 27 November 2023

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

[Ni(cyclam-trzbpy)Ru(bpy)2][PF6]4

0.03




H2O



ascorbate 0.1 6.5 450 60 5.2 2 72.2%; 0%; 27.8%; 0%; 0%


No