Pyranopterin Related Dithiolene Molybdenum Complexes as Homogeneous Catalysts for CO2 Photoreduction/Table 1

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[MoO(qpdt)2][NBu4]2	0.05	Ru(bpy)3Cl2	0.5	BIH	0.1			MeCN	TEOA		5:1							20	400	15	73						670			80						8.9%; 0%; 81.4%; 9.7%; 0%			Yes
[K]2[MoO(Hqpdt)2]	0.05	Ru(bpy)3Cl2	0.5	BIH	0.1			MeCN	TEOA		5:1							20	400	15	13						51			31						13.7%; 0%; 53.7%; 32.6%; 0%			Yes
[MoO(2Hqpdt)2][NBu4]	0.05	Ru(bpy)3Cl2	0.5	BIH	0.1			MeCN	TEOA		5:1							20	400	15	40						89			83						18.9%; 0%; 42.0%; 39.2%; 0%			Yes