Light-Driven Reduction of CO2 to CO in Water with a Cobalt Molecular Catalyst and an Organic Sensitizer/Photocatalytic CO2 Reduction by 1 (2 μM) in CO2-Saturated Aqueous CH3CN Solutions: Difference between revisions

Revision as of 14:13, 17 November 2023

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solv A/B/C	additives	λexc [nm]	TON CO	TON H2	TON HCOOH	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	include
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	100/0		450	2332	106	1370	61.2%; 0%; 2.8%; 36.0%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	95/5		450	6228	304	2441	69.4%; 0%; 3.4%; 27.2%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	90/10		450	14691	283	1097	91.4%; 0%; 1.8%; 6.8%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	85/15		450	15822	220	1147	92.0%; 0%; 1.3%; 6.7%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	80/20		450	18989	227	1215	92.9%; 0%; 1.1%; 5.9%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	80/20	Hg	450	19646	226	415	96.8%; 0%; 1.1%; 2.0%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O	100/0		450	183	9	419	30.0%; 0%; 1.5%; 68.6%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O	95/5		450	612	202	51	70.8%; 0%; 23.4%; 5.9%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O	90/10		450	515	253	46	63.3%; 0%; 31.1%; 5.7%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O	85/15		450	3171	498	179	82.4%; 0%; 12.9%; 4.7%; 0%	No

@@ Line 102: / Line 102: @@
 |TON H2=226
 |TON HCOOH=415
+|include=No
+}}{{Photocatalytic CO2 conversion
+|catalyst=Molecule:100788
+|cat conc=0.002
+|PS=Molecule:100797
+|PS conc=0.2
+|e-D=Molecule:100508
+|e-D conc=0.1
+|H-D=Molecule:100505
+|H-D conc=0.15
+|solvent A=Molecule:100530
+|solvent B=Molecule:100616
+|solvent-ratio=100/0
+|λexc=450
+|TON CO=183
+|TON H2=9
+|TON HCOOH=419
+|include=No
+}}{{Photocatalytic CO2 conversion
+|catalyst=Molecule:100788
+|cat conc=0.002
+|PS=Molecule:100797
+|PS conc=0.2
+|e-D=Molecule:100508
+|e-D conc=0.1
+|H-D=Molecule:100505
+|H-D conc=0.15
+|solvent A=Molecule:100530
+|solvent B=Molecule:100616
+|solvent-ratio=95/5
+|λexc=450
+|TON CO=612
+|TON H2=202
+|TON HCOOH=51
+|include=No
+}}{{Photocatalytic CO2 conversion
+|catalyst=Molecule:100788
+|cat conc=0.002
+|PS=Molecule:100797
+|PS conc=0.2
+|e-D=Molecule:100508
+|e-D conc=0.1
+|H-D=Molecule:100505
+|H-D conc=0.15
+|solvent A=Molecule:100530
+|solvent B=Molecule:100616
+|solvent-ratio=90/10
+|λexc=450
+|TON CO=515
+|TON H2=253
+|TON HCOOH=46
+|include=No
+}}{{Photocatalytic CO2 conversion
+|catalyst=Molecule:100788
+|cat conc=0.002
+|PS=Molecule:100797
+|PS conc=0.2
+|e-D=Molecule:100508
+|e-D conc=0.1
+|H-D=Molecule:100505
+|H-D conc=0.15
+|solvent A=Molecule:100530
+|solvent B=Molecule:100616
+|solvent-ratio=85/15
+|λexc=450
+|TON CO=3171
+|TON H2=498
+|TON HCOOH=179
 |include=No
 }}
 }}