Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes/Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2: Difference between revisions

Revision as of 12:07, 11 August 2023

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN											460 (LED)	1.33	2660		98				23		1	35		1				97.9%; 0%; 0.8%; 1.3%; 0%	100		No

@@ Line 2: / Line 2: @@
 |experiments={{Photocatalytic CO2 conversion
 |catalyst=Molecule:100788
+|cat conc=0.005
+|PS=Molecule:100787
+|PS conc=0.3
+|e-D=Molecule:100508
+|e-D conc=0.1
+|H-D=Molecule:100507
+|H-D conc=0.5
+|solvent A=Molecule:100530
+|λexc=460 (LED)
+|irr time=1.33
+|TON CO=2660
+|Φ CO=98
+|TON H2=23
+|Φ H2=1
+|TON HCOOH=35
+|Φ HCOOH=1
 |include=No
 }}
 }}