Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction/Table 1

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Re(bpy)(CO)3(MeCN)][PF6]	0.05		0.05					DMF	TEOA		5:1								436	1	27		0.53													n/a	0.53		Yes
[Re(bpy)(CO)3(MeCN)][PF6]	0.05		0.05					DMF	TEOA		5:1								436	15	98															n/a			Yes
[Re(bpy)(CO)3(MeCN)][PF6]	0.05		0.05					DMF	TEOA		5:1								436	1	22		0.61													n/a	0.61		Yes
[Re(bpy)(CO)3(MeCN)][PF6]	0.05		0.05					DMF	TEOA		5:1								436	15	71															n/a			Yes
			0.05					DMF	TEOA		5:1								436	1	6															n/a			Yes
			0.05					DMF	TEOA		5:1								436	15	8															n/a			Yes
[Re(bpy)(CO)3(MeCN)][PF6]	0.05		0.05					DMF	TEOA		5:1								436	1	20		0.60													n/a	0.6		Yes
[Re(bpy)(CO)3(MeCN)][PF6]	0.05		0.05					DMF	TEOA		5:1								436	15	32															n/a			Yes
[Re(bpy)(CO)3(MeCN)][PF6]	0.05		0.05					DMF	TEOA		5:1								436	1	11		0.60													n/a	0.6		Yes
[Re(bpy)(CO)3(MeCN)][PF6]	0.05		0.05					DMF	TEOA		5:1								436	15	48															n/a			Yes