A Dinuclear Cobalt Cryptate as a Homogeneous Photocatalyst for Highly Selective and Efficient Visible-Light Driven CO2 Reduction to CO in CH3CN-H2O Solution/Best result and control experiments: Difference between revisions

Revision as of 13:48, 28 July 2023

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
100776	0.000025	100777	0.4	TEOA	300			MeCN	H2O		4:1							25	450 nm (LED, 100 mW.cm^-2)	10	16896	0.47	98				368	0.01	2							97.9%; 0%; 2.1%; 0%; 0%	100		Yes
100776	0.0005	100777	0.4	TEOA	300			MeCN	H2O		4:1							25	450 nm (LED, 100 mW.cm^-2)	10	684	0.019	92				56	0.0016	8							92.4%; 0%; 7.6%; 0%; 0%	100		No

cat	cat_abb	cat conc [mM]	solvent A	solvent B	solvent-ratio [SolvA/SolvB]	pH	Temperature [° C]	λexc [nm]	include
100776		0,000025	CH3CN	H2O	4:1		25	450	No

@@ Line 20: / Line 20: @@
 |Φ H2=2
 |include=Yes
+}}{{Photocatalytic CO2 conversion
+|catalyst=100776
+|cat conc=0.0005
+|PS=100777
+|PS conc=0.4
+|e-D=Molecule:100507
+|e-D conc=300
+|solvent A=Molecule:100530
+|solvent B=Molecule:100616
+|solvent-ratio=4:1
+|Temperature=25
+|λexc=450 nm (LED, 100 mW.cm^-2)
+|irr time=10
+|TON CO=684
+|TOF CO=0.019
+|Φ CO=92
+|TON H2=56
+|TOF H2=0.0016
+|Φ H2=8
+|include=No
 }}
 }}