A Dinuclear Cobalt Cryptate as a Homogeneous Photocatalyst for Highly Selective and Efficient Visible-Light Driven CO2 Reduction to CO in CH3CN-H2O Solution/Best result and control experiments: Difference between revisions

Revision as of 13:22, 28 July 2023

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
	0.000025		0.4	TEOA	300			MeCN	H2O		4:1							25	450 nm (LED, 100 mW.cm^-2)	10	16896	0.47	98				368	0.01	2							97.9%; 0%; 2.1%; 0%; 0%	100		Yes

cat	cat_abb	cat conc [mM]	solvent A	solvent B	solvent-ratio [SolvA/SolvB]	pH	Temperature [° C]	λexc [nm]	include
100776		0,000025	CH3CN	H2O	4:1		25	450	No

@@ Line 1: / Line 1: @@
+{{Photocatalytic CO2 conversion experiments
+|experiments={{Photocatalytic CO2 conversion
+|cat conc=0.000025
+|PS conc=0.4
+|e-D=TEOA
+|e-D conc=300
+|solvent A=MeCN
+|solvent B=H2O
+|solvent-ratio=4:1
+|Temperature=25
+|λexc=450 nm (LED, 100 mW.cm^-2)
+|irr time=10
+|TON CO=16896
+|TOF CO=0.47
+|Φ CO=98
+|TON H2=368
+|TOF H2=0.01
+|Φ H2=2
+|include=Yes
+}}
+}}
 {{DemoExperiment2
 |title=Table 1