Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore/Photocatalytic CO2 reduction: best results: Difference between revisions
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< Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
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|TOF CO=7650 | |TOF CO=7650 | ||
|TON H2=843 | |TON H2=843 | ||
|include=Yes | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.0002 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.1 | |||
|solvent A=Molecule:100529 | |||
|λexc=>400 | |||
|irr time=1 | |||
|TON CO=4.4 | |||
|TOF CO=4.3 | |||
|include=Yes | |include=Yes | ||
}} | }} | ||
}} | }} | ||
Revision as of 09:45, 12 July 2023
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.0002 | 0.1 | 0.01 |
|
|
|
>400 | 7 | 4779 | 1356 | 270 | 94.7%; 0%; 5.3%; 0%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.0002 | 0.1 | 0.1 |
|
|
|
>400 | 23 | 16109 | 7650 | 843 | 95.0%; 0%; 5.0%; 0%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.0002 |
|
0.1 |
|
|
|
>400 | 1 | 4.4 | 4.3 | n/a |
|
Yes |
