Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study/Table 1: Difference between revisions

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|TON CO=103
|TON CO=103
|TON H2=25
|TON H2=25
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100614
|cat conc=0.002
|PS=Molecule:100761
|PS conc=0.2
|e-D=Molecule:100508
|e-D conc=0.005
|solvent A=Molecule:100530
|additives=TFE
|additives conc=0.1
|λexc=> 400
|irr time=21
|TON CO=88
|TON H2=12
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100614
|cat conc=0.002
|PS=Molecule:100762
|PS conc=0.2
|e-D=Molecule:100508
|e-D conc=0.005
|solvent A=Molecule:100530
|additives=TFE
|additives conc=0.1
|λexc=> 400
|irr time=21
|TON CO=115
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100614
|cat conc=0.002
|PS=Molecule:100763
|PS conc=0.2
|e-D=Molecule:100508
|e-D conc=0.005
|solvent A=Molecule:100530
|additives=TFE
|additives conc=0.1
|λexc=> 400
|irr time=21
|TON CO=112
|TON H2=12
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100614
|cat conc=0.002
|PS=Molecule:100764
|PS conc=0.2
|e-D=Molecule:100508
|e-D conc=0.005
|solvent A=Molecule:100530
|additives=TFE
|additives conc=0.1
|λexc=> 400
|irr time=21
|TON CO=32
|TON H2=57
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100614
|cat conc=0.002
|PS=Molecule:100765
|PS conc=0.2
|e-D=Molecule:100508
|e-D conc=0.005
|solvent A=Molecule:100530
|additives=TFE
|additives conc=0.1
|λexc=> 400
|irr time=21
|TON CO=89
|include=Yes
|include=Yes
}}
}}
}}
}}

Revision as of 09:35, 28 June 2023

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100614

0.002

Molecule:100493

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 103 25 80.5%; 0%; 19.5%; 0%; 0%


Yes

Molecule:100614

0.002

Molecule:100761

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 88 12 88.0%; 0%; 12.0%; 0%; 0%


Yes

Molecule:100614

0.002

Molecule:100762

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 115 n/a


Yes

Molecule:100614

0.002

Molecule:100763

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 112 12 90.3%; 0%; 9.7%; 0%; 0%


Yes

Molecule:100614

0.002

Molecule:100764

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 32 57 36.0%; 0%; 64.0%; 0%; 0%


Yes

Molecule:100614

0.002

Molecule:100765

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 89 n/a


Yes