Photocatalytic CO2 Reduction under Visible-Light Irradiation by Ruthenium CNC Pincer Complexes/Conditions optimizations for photocatalytic reduction of CO2: Difference between revisions
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< Photocatalytic CO2 Reduction under Visible-Light Irradiation by Ruthenium CNC Pincer Complexes
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
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| Line 74: | Line 74: | ||
|λexc=450 W HG lamp, K2CrO4 filter | |λexc=450 W HG lamp, K2CrO4 filter | ||
|irr time=24 | |irr time=24 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 90: | Line 87: | ||
|TON CO=8.9 | |TON CO=8.9 | ||
|TON H2=87 | |TON H2=87 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 102: | Line 98: | ||
|λexc=450 W HG lamp, K2CrO4 filter | |λexc=450 W HG lamp, K2CrO4 filter | ||
|irr time=24 | |irr time=24 | ||
|TON H2=20 | |TON H2=20 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 118: | Line 112: | ||
|λexc=450 W HG lamp, K2CrO4 filter | |λexc=450 W HG lamp, K2CrO4 filter | ||
|irr time=24 | |irr time=24 | ||
|TON H2=307 | |TON H2=307 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 132: | Line 124: | ||
|solvent B=Molecule:100507 | |solvent B=Molecule:100507 | ||
|solvent-ratio=4:1 | |solvent-ratio=4:1 | ||
|λexc= | |λexc=dark | ||
|include=No | |include=No | ||
}} | }} | ||
}} | }} | ||
Revision as of 10:50, 3 May 2023
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.01 | 0.05 | 0.1 |
|
|
4:1 | 450 W HG lamp, K2CrO4 filter | 24 | 129 | 556 | 3296 | 3.2%; 0%; 14.0%; 82.8%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.01 | 0.05 | 0.1 |
|
|
4:1 | 450 W HG lamp, K2CrO4 filter | 24 | 224 | 1438 | 4593 | 3.6%; 0%; 23.0%; 73.4%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.01 | 0.05 | 0.1 |
|
|
4:1 | 450 W HG lamp, K2CrO4 filter | 24 | 129 | 505 | 3792 | 2.9%; 0%; 11.4%; 85.7%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.01 | 0.05 | 0.1 |
|
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4:1 | 450 W HG lamp, K2CrO4 filter | 24 | 300 | 1897 | 5634 | 3.8%; 0%; 24.2%; 71.9%; 0% |
|
Yes | ||||||||||||||||||||||||||
|
|
0.05 | 0.1 |
|
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4:1 | 450 W HG lamp, K2CrO4 filter | 24 | n/a |
|
No | |||||||||||||||||||||||||||||
| 0.01 |
|
0.1 |
|
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4:1 | 450 W HG lamp, K2CrO4 filter | 24 | 8.9 | 87 | 9.3%; 0%; 90.7%; 0%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.01 | 0.05 |
|
|
|
4:1 | 450 W HG lamp, K2CrO4 filter | 24 | 20 | n/a |
|
No | ||||||||||||||||||||||||||||
| 0.01 | 0.05 | 0.1 |
|
|
4:1 | 450 W HG lamp, K2CrO4 filter | 24 | 307 | n/a |
|
No | ||||||||||||||||||||||||||||
| 0.01 | 0.05 | 0.1 |
|
|
4:1 | dark | n/a |
|
No |
