Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH/Table 1

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Mn(phdk)(CO)3Br		Ru(bpy)3	100	BNAH	0.1			MeCN	TEOA		4:1								480	16	8									52						13.3%; 0%; 0%; 86.7%; 0%			Yes
Mn(phdk)(CO)3(MeCN)		Ru(bpy)3	100	BNAH	0.1			MeCN	TEOA		4:1								480	24	15									58						20.5%; 0%; 0%; 79.5%; 0%			Yes
Mn(phdk)(CO)3(MeCN)		Ru(bpy)3	100	BNAH	0.1			MeCN	TEOA		4:1								480	16	9									48						15.8%; 0%; 0%; 84.2%; 0%			Yes
		Ru(bpy)3	100	BNAH	0.1			MeCN	TEOA		4:1								480	16	47									15						75.8%; 0%; 0%; 24.2%; 0%			Yes
Mn(phdk)(CO)3(MeCN)		Ru(bpy)3	100	BNAH	0.1			MeCN	TEOA		4:1								500	16	7									40						14.9%; 0%; 0%; 85.1%; 0%			Yes
Mn(phdk)(CO)3(MeCN)		Ru(bpy)3	100	BNAH	0.1			MeCN	TEOA		4:1								457	16	7									34						17.1%; 0%; 0%; 82.9%; 0%			Yes
Mn(phdk)(CO)3(MeCN)	2	Ru(bpy)3	100	BNAH	0.1			MeCN	TEOA		4:1								480	16	5									18						21.7%; 0%; 0%; 78.3%; 0%			Yes
Mn(phdk)(CO)3(MeCN)		Ru(bpy)3	200	BNAH	0.1			MeCN	TEOA		4:1								480	16	8									52						13.3%; 0%; 0%; 86.7%; 0%			Yes
Mn(phdk)(CO)3(MeCN)		Ru(bpy)3	100	BNAH	0.1			MeCN	TEOA	H2O	4:1								480	16																n/a			No
Mn(phdk)(CO)3(MeCN)		Ru(bpy)3	100	BNAH	0.1			MeCN		H2O									500	16																n/a			No
Mn(phdk)(CO)3(MeCN)		Ru(bpy)3	100					MeCN	TEOA		4:1								480	16	3															n/a			No