Photocatalytic CO2 reduction using a Mn complex as a catalyst/Photocatalytic CO2 reduction: conditions optimization: Difference between revisions
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< Photocatalytic CO2 reduction using a Mn complex as a catalyst
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
(Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100688 |cat conc=0.05 |PS=Molecule:100694 |PS conc=0.05 |e-D=Molecu...") |
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|TON H2=4 | |TON H2=4 | ||
|TON HCOOH=8 | |TON HCOOH=8 | ||
|include=Yes | |||
}}{{Photocatalytic CO2 conversion | |||
|PS=Molecule:100694 | |||
|PS conc=0.05 | |||
|e-D=Molecule:100509 | |||
|e-D conc=0.1 | |||
|solvent A=Molecule:100529 | |||
|solvent B=Molecule:100507 | |||
|solvent-ratio=4:1 | |||
|λexc=480 | |||
|irr time=12 | |||
|TON CO=3 | |||
|TON H2=11 | |||
|TON HCOOH=25 | |||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 85: | Line 99: | ||
|solvent A=Molecule:100529 | |solvent A=Molecule:100529 | ||
|solvent B=Molecule:100507 | |solvent B=Molecule:100507 | ||
|solvent-ratio=4: | |solvent-ratio=4:1 | ||
|λexc=480 | |||
|irr time=12 | |||
|TON CO=3 | |||
|TON HCOOH=1 | |||
|include=No | |include=No | ||
}} | }} | ||
}} | }} | ||
Revision as of 11:57, 14 February 2023
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume [mL] | intensity [kW/m²] | pH | T [] | λexc [nm] | t [h] | TON CO | TOF CO [TOF/min] | Φ CO [%] | TON CH4 | TOF CH4 [TOF/min] | Φ CH4 [%] | TON H2 | TOF H2 [TOF/min] | Φ H2 [%] | TON HCOOH | TOF HCOOH [TOF/min] | Φ HCOOH [%] | TON MeOH | TOF MeOH [TOF/min] | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.05 | 0.05 | 0.1 |
|
|
4:1 | 480 | 0.17 | 2 | 4 | 33.3%; 0%; 0%; 66.7%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.05 | 0.05 | 0.1 |
|
|
4:1 | 480 | 2 | 8 | 1 | 67 | 10.5%; 0%; 1.3%; 88.2%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.05 | 0.1 |
|
|
4:1 | 480 | 12 | 12 | 14 | 149 | 6.9%; 0%; 8.0%; 85.1%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.05 | 0.1 |
|
|
4:1 | Argon atmosphere | 480 | 12 | 2 | 49 | 4 | 3.6%; 0%; 89.1%; 7.3%; 0% |
|
Yes | |||||||||||||||||||||||||
|
|
0.05 | 0.1 |
|
|
4:1 | 480 | 2 | 1 | 4 | 8 | 7.7%; 0%; 30.8%; 61.5%; 0% |
|
Yes | ||||||||||||||||||||||||||
|
|
0.05 | 0.1 |
|
|
4:1 | 480 | 12 | 3 | 11 | 25 | 7.7%; 0%; 28.2%; 64.1%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 |
|
0.1 |
|
|
4:1 | 480 | 12 | 3 | 1 | 75.0%; 0%; 0%; 25.0%; 0% |
|
No |
