Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO2-to-CO conversion under visible light/inv0: Difference between revisions

Revision as of 17:33, 19 June 2026

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	solvent B	solv A/B/C	feedstock gas	intensity [kW/m²]	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON H2	TOF H2 [TOF/min]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]
[[[Fe(bpzphen)(H2O)2](BF4)2 (Fe1) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	987	41.1 h−1		187		84.1%; 0%; 15.9%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzphen)(H2O)2](BF4)2 (Fe1)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	1318	54.9 h−1		243		84.4%; 0%; 15.6%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	847	35.3 h−1		205		80.5%; 0%; 19.5%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	1265	52.7 h−1		133		90.5%; 0%; 9.5%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	4 h	311	77.7 h−1		51		85.9%; 0%; 14.1%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	48 h	1578	32.9 h−1		296		84.2%; 0%; 15.8%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	96 h	1593	16.6 h−1		300		84.2%; 0%; 15.8%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN			CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	2	< 0.1 h−1		22		8.3%; 0%; 91.7%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	10% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	1352	56.3 h−1		285		82.6%; 0%; 17.4%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	30% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	661	27.5 h−1		191		77.6%; 0%; 22.4%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	50% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	621	25.8 h−1		77		89.0%; 0%; 11.0%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	25.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	2086	86.9 h−1		123		94.4%; 0%; 5.6%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	12.5 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	4259	177.4 h−1		276		93.9%; 0%; 6.1%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	6.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	10	168		423.7 h−1	862	n/a		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	3.12 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	23	138		964.1 h−1	2177	n/a		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzphen)(H2O)2](BF4)2 (Fe1) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated	absorbed photon flux 2.16 × 10−8 einstein s−1	35 °C	462 nm	4 h			4.8%			n/a	4.8	<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzphen)(H2O)2](BF4)2 (Fe1)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"absorbedphotonflux" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated	absorbed photon flux 2.16 × 10−8 einstein s−1	35 °C	462 nm	4 h	9754	2438 h−1	7.6%			n/a	7.6	<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"absorbedphotonflux" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated	absorbed photon flux 2.16 × 10−8 einstein s−1	35 °C	462 nm	4 h			3.8%			n/a	3.8	<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"absorbedphotonflux" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>
[[[Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated	absorbed photon flux 2.16 × 10−8 einstein s−1	35 °C	462 nm	4 h			7.2%			n/a	7.2	<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"absorbedphotonflux" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	27.5 mM	MeCN	H2O	7.5% H2O (v/v)	CO2-saturated		35 °C	462 nm (blue LED strip)	24 h	221					n/a		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>

@@ Line 8: / Line 8: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 14: / Line 14: @@
 |irr time=24 h
 |Turnover_number__CO=987
-|Turnover_frequency__CO=41.1 h-1
+|Turnover_frequency__CO=41.1 h−1
 |Turnover_number__H2=187
 |Turnover_frequency__H2=
@@ Line 39: / Line 39: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 45: / Line 45: @@
 |irr time=24 h
 |Turnover_number__CO=1318
-|Turnover_frequency__CO=54.9 h-1
+|Turnover_frequency__CO=54.9 h−1
 |Turnover_number__H2=243
 |Turnover_frequency__H2=
@@ Line 70: / Line 70: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 76: / Line 76: @@
 |irr time=24 h
 |Turnover_number__CO=847
-|Turnover_frequency__CO=35.3 h-1
+|Turnover_frequency__CO=35.3 h−1
 |Turnover_number__H2=205
 |Turnover_frequency__H2=
@@ Line 101: / Line 101: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 107: / Line 107: @@
 |irr time=24 h
 |Turnover_number__CO=1265
-|Turnover_frequency__CO=52.7 h-1
+|Turnover_frequency__CO=52.7 h−1
 |Turnover_number__H2=133
 |Turnover_frequency__H2=
@@ Line 132: / Line 132: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 138: / Line 138: @@
 |irr time=4 h
 |Turnover_number__CO=311
-|Turnover_frequency__CO=77.7 h-1
+|Turnover_frequency__CO=77.7 h−1
 |Turnover_number__H2=51
 |Turnover_frequency__H2=
@@ Line 163: / Line 163: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 169: / Line 169: @@
 |irr time=48 h
 |Turnover_number__CO=1578
-|Turnover_frequency__CO=32.9 h-1
+|Turnover_frequency__CO=32.9 h−1
 |Turnover_number__H2=296
 |Turnover_frequency__H2=
@@ Line 194: / Line 194: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 200: / Line 200: @@
 |irr time=96 h
 |Turnover_number__CO=1593
-|Turnover_frequency__CO=16.6 h-1
+|Turnover_frequency__CO=16.6 h−1
 |Turnover_number__H2=300
 |Turnover_frequency__H2=
@@ Line 231: / Line 231: @@
 |irr time=24 h
 |Turnover_number__CO=2
-|Turnover_frequency__CO=< 0.1 h-1
+|Turnover_frequency__CO=< 0.1 h−1
 |Turnover_number__H2=22
 |Turnover_frequency__H2=
@@ Line 256: / Line 256: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=90:10
+|solvent-ratio=10% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 262: / Line 262: @@
 |irr time=24 h
 |Turnover_number__CO=1352
-|Turnover_frequency__CO=56.3 h-1
+|Turnover_frequency__CO=56.3 h−1
 |Turnover_number__H2=285
 |Turnover_frequency__H2=
@@ Line 287: / Line 287: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=70:30
+|solvent-ratio=30% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 293: / Line 293: @@
 |irr time=24 h
 |Turnover_number__CO=661
-|Turnover_frequency__CO=27.5 h-1
+|Turnover_frequency__CO=27.5 h−1
 |Turnover_number__H2=191
 |Turnover_frequency__H2=
@@ Line 318: / Line 318: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=50:50
+|solvent-ratio=50% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 324: / Line 324: @@
 |irr time=24 h
 |Turnover_number__CO=621
-|Turnover_frequency__CO=25.8 h-1
+|Turnover_frequency__CO=25.8 h−1
 |Turnover_number__H2=77
 |Turnover_frequency__H2=
@@ Line 349: / Line 349: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 355: / Line 355: @@
 |irr time=24 h
 |Turnover_number__CO=2086
-|Turnover_frequency__CO=86.9 h-1
+|Turnover_frequency__CO=86.9 h−1
 |Turnover_number__H2=123
 |Turnover_frequency__H2=
@@ Line 380: / Line 380: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
@@ Line 386: / Line 386: @@
 |irr time=24 h
 |Turnover_number__CO=4259
-|Turnover_frequency__CO=177.4 h-1
+|Turnover_frequency__CO=177.4 h−1
 |Turnover_number__H2=276
 |Turnover_frequency__H2=
@@ Line 411: / Line 411: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
-|Turnover_number__CO=10168
+|Turnover_number__CO=10
-|Turnover_frequency__CO=423.7 h-1
+|Turnover_frequency__CO=168
-|Turnover_number__H2=862
+|Turnover_number__H2=423.7 h−1
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=862
 |additives=
 |Turnover_number__HCOOH=
@@ Line 442: / Line 442: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
-|Turnover_number__CO=23138
+|Turnover_number__CO=23
-|Turnover_frequency__CO=964.1 h-1
+|Turnover_frequency__CO=138
-|Turnover_number__H2=2177
+|Turnover_number__H2=964.1 h−1
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=2177
 |additives=
 |Turnover_number__HCOOH=
 |intensity=
-|Turnover_number__CH4=
-|additives conc=
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
-}}
-{{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=3.12 μM
-|PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
-|e-D=Molecule:100508
-|e-D conc=0.11 M
-|solvent A=Molecule:100530
-|solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
-|Temperature=35 °C
-|λexc=462 nm (blue LED strip)
-|irr time=2 h
-|Turnover_number__CO=3562
-|Turnover_frequency__CO=
-|Turnover_number__H2=1039
-|Turnover_frequency__H2=
-|additives=
-|Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10^-8 einstein s^-1
-|Turnover_number__CH4=
-|additives conc=
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
-}}
-{{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=3.12 μM
-|PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
-|e-D=Molecule:100508
-|e-D conc=0.11 M
-|solvent A=Molecule:100530
-|solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
-|Temperature=35 °C
-|λexc=462 nm (blue LED strip)
-|irr time=4 h
-|Turnover_number__CO=9754
-|Turnover_frequency__CO=2438 h-1
-|Turnover_number__H2=1732
-|Turnover_frequency__H2=
-|additives=
-|Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10^-8 einstein s^-1
-|Turnover_number__CH4=
-|additives conc=
-|Quantum_yield__CO=7.6 % at 462 nm
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
-}}
-{{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=3.12 μM
-|PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
-|e-D=Molecule:100508
-|e-D conc=0.11 M
-|solvent A=Molecule:100530
-|solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
-|Temperature=35 °C
-|λexc=462 nm (blue LED strip)
-|irr time=72 h
-|Turnover_number__CO=25872
-|Turnover_frequency__CO=
-|Turnover_number__H2=3899
-|Turnover_frequency__H2=
-|additives=
-|Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10^-8 einstein s^-1
 |Turnover_number__CH4=
 |additives conc=
@@ Line 566: / Line 473: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
-|λexc=462 nm (blue LED strip)
+|λexc=462 nm
 |irr time=4 h
-|Turnover_number__CO=5900
+|Turnover_number__CO=
 |Turnover_frequency__CO=
-|Turnover_number__H2=1700
+|Turnover_number__H2=
 |Turnover_frequency__H2=
 |additives=
 |Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10^-8 einstein s^-1
+|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
 |Turnover_number__CH4=
 |additives conc=
-|Quantum_yield__CO=4.8 %
+|Quantum_yield__CO=4.8%
 |H-D=
 |H-D conc=
@@ Line 597: / Line 504: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
-|λexc=462 nm (blue LED strip)
+|λexc=462 nm
 |irr time=4 h
 |Turnover_number__CO=9754
-|Turnover_frequency__CO=
+|Turnover_frequency__CO=2438 h−1
-|Turnover_number__H2=2600
+|Turnover_number__H2=
 |Turnover_frequency__H2=
 |additives=
 |Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10^-8 einstein s^-1
+|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
 |Turnover_number__CH4=
 |additives conc=
-|Quantum_yield__CO=7.6 %
+|Quantum_yield__CO=7.6%
 |H-D=
 |H-D conc=
@@ Line 628: / Line 535: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
-|λexc=462 nm (blue LED strip)
+|λexc=462 nm
 |irr time=4 h
-|Turnover_number__CO=4700
+|Turnover_number__CO=
 |Turnover_frequency__CO=
-|Turnover_number__H2=1000
+|Turnover_number__H2=
 |Turnover_frequency__H2=
 |additives=
 |Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10^-8 einstein s^-1
+|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
 |Turnover_number__CH4=
 |additives conc=
-|Quantum_yield__CO=3.8 %
+|Quantum_yield__CO=3.8%
 |H-D=
 |H-D conc=
@@ Line 659: / Line 566: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C
-|λexc=462 nm (blue LED strip)
+|λexc=462 nm
 |irr time=4 h
-|Turnover_number__CO=9000
+|Turnover_number__CO=
 |Turnover_frequency__CO=
-|Turnover_number__H2=2300
+|Turnover_number__H2=
 |Turnover_frequency__H2=
 |additives=
 |Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10^-8 einstein s^-1
+|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
 |Turnover_number__CH4=
 |additives conc=
-|Quantum_yield__CO=7.2 %
+|Quantum_yield__CO=7.2%
 |H-D=
 |H-D conc=
@@ Line 690: / Line 597: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=92.5:7.5
+|solvent-ratio=7.5% H2O (v/v)
 |feedstock gas=CO2-saturated
 |Temperature=35 °C

Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO2-to-CO conversion under visible light/inv0: Difference between revisions

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