Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH/Photocatalytic CO2 reduction with the Mn complexes under various conditions.: Difference between revisions

Latest revision as of 13:33, 29 January 2026

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	λexc [nm]	t [h]	TON CO	TON HCOOH	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	include
Mn(phdk)(CO)3Br	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	TEOA		4:1		480	16	8	52	13.3%; 0%; 0%; 86.7%; 0%	Yes
Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	TEOA		4:1		480	24	15	58	20.5%; 0%; 0%; 79.5%; 0%	Yes
Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	TEOA		4:1		480	16	9	48	15.8%; 0%; 0%; 84.2%; 0%	Yes
Mn(bpy)(CO)3Br	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	TEOA		4:1		480	16	47	15	75.8%; 0%; 0%; 24.2%; 0%	Yes
Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	TEOA		4:1		500	16	7	40	14.9%; 0%; 0%; 85.1%; 0%	Yes
Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	TEOA		4:1		457	16	7	34	17.1%; 0%; 0%; 82.9%; 0%	Yes
Mn(phdk)(CO)3(MeCN)	200	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	TEOA		4:1		480	16	5	18	21.7%; 0%; 0%; 78.3%; 0%	Yes
Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	200	BNAH	0.1	MeCN	TEOA		4:1		480	16	8	52	13.3%; 0%; 0%; 86.7%; 0%	Yes
Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	TEOA	H2O	4:1		480	16			n/a	No
Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		H2O			500	16			n/a	No
Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100			MeCN	TEOA		4:1		480	16	3		n/a	No
Mn(phdk)(CO)3(MeCN)	100			BNAH	0.1	MeCN	TEOA		4:1		500	16			n/a	No
Mn(phdk)(CO)3Br	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	TEOA		4:1	Argon gas	480	16			n/a	No
		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	TEOA		4:1		480	16			n/a	No
		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	TEOA		4:1		480	16			n/a	No
Mn(phdk)(CO)3Br	100	Ru(bpy)3Cl2	100	BNAH	0.1	DMF	TEOA		4:1		480	16	21	22	48.8%; 0%; 0%; 51.2%; 0%	Yes
Mn(phdk)(CO)3Br	100	Ru(bpy)3Cl2	100	BNAH	0.1	DMF					480	16	2		n/a	No
Mn(phdk)(CO)3Br	100	Ru(bpy)3Cl2	100			DMF	TEOA				480	16	9	13	40.9%; 0%; 0%; 59.1%; 0%	Yes
Mn(phen)(CO)3Br	100	Ru(bpy)3Cl2	100	BNAH	0.1	DMF	TEOA		4:1		480	16	17	4	81.0%; 0%; 0%; 19.0%; 0%	Yes
Mn(bpy)(CO)3Br	100	Ru(bpy)3Cl2	100	BNAH	0.1	DMF	TEOA		4:1		480	16	6	39	13.3%; 0%; 0%; 86.7%; 0%	Yes
Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100			H2O				ascorbic acid/NaA	480	16			n/a	No
Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100			H2O	TEOA			ascorbic acid/NaA	500	16			n/a	No

@@ Line 12: / Line 12: @@
 |λexc=480
 |irr time=16
-|TON CO=8
+|Turnover_number__CO=8
-|TON HCOOH=52
+|Turnover_number__HCOOH=52
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 27: / Line 27: @@
 |λexc=480
 |irr time=24
-|TON CO=15
+|Turnover_number__CO=15
-|TON HCOOH=58
+|Turnover_number__HCOOH=58
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 42: / Line 42: @@
 |λexc=480
 |irr time=16
-|TON CO=9
+|Turnover_number__CO=9
-|TON HCOOH=48
+|Turnover_number__HCOOH=48
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 57: / Line 57: @@
 |λexc=480
 |irr time=16
-|TON CO=47
+|Turnover_number__CO=47
-|TON HCOOH=15
+|Turnover_number__HCOOH=15
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 72: / Line 72: @@
 |λexc=500
 |irr time=16
-|TON CO=7
+|Turnover_number__CO=7
-|TON HCOOH=40
+|Turnover_number__HCOOH=40
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 87: / Line 87: @@
 |λexc=457
 |irr time=16
-|TON CO=7
+|Turnover_number__CO=7
-|TON HCOOH=34
+|Turnover_number__HCOOH=34
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 102: / Line 102: @@
 |λexc=480
 |irr time=16
-|TON CO=5
+|Turnover_number__CO=5
-|TON HCOOH=18
+|Turnover_number__HCOOH=18
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 117: / Line 117: @@
 |λexc=480
 |irr time=16
-|TON CO=8
+|Turnover_number__CO=8
-|TON HCOOH=52
+|Turnover_number__HCOOH=52
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 156: / Line 156: @@
 |λexc=480
 |irr time=16
-|TON CO=3
+|Turnover_number__CO=3
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 217: / Line 217: @@
 |λexc=480
 |irr time=16
-|TON CO=21
+|Turnover_number__CO=21
-|TON HCOOH=22
+|Turnover_number__HCOOH=22
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 230: / Line 230: @@
 |λexc=480
 |irr time=16
-|TON CO=2
+|Turnover_number__CO=2
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 241: / Line 241: @@
 |λexc=480
 |irr time=16
-|TON CO=9
+|Turnover_number__CO=9
-|TON HCOOH=13
+|Turnover_number__HCOOH=13
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 256: / Line 256: @@
 |λexc=480
 |irr time=16
-|TON CO=17
+|Turnover_number__CO=17
-|TON HCOOH=4
+|Turnover_number__HCOOH=4
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 271: / Line 271: @@
 |λexc=480
 |irr time=16
-|TON CO=6
+|Turnover_number__CO=6
-|TON HCOOH=39
+|Turnover_number__HCOOH=39
 |include=Yes
 }}{{Photocatalytic CO2 conversion

Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH/Photocatalytic CO2 reduction with the Mn complexes under various conditions.: Difference between revisions

Latest revision as of 13:33, 29 January 2026

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