Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes/Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2: Difference between revisions
From ChemWiki
investigation
No edit summary |
Jana.alpin (talk | contribs) No edit summary |
||
| Line 2: | Line 2: | ||
|experiments={{Photocatalytic CO2 conversion | |experiments={{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.2 | |PS conc=0.2 | ||
| Line 18: | Line 18: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.2 | |PS conc=0.2 | ||
| Line 51: | Line 51: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=20 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.2 | |PS conc=0.2 | ||
| Line 67: | Line 67: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=20 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.2 | |PS conc=0.2 | ||
| Line 84: | Line 84: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.2 | |PS conc=0.2 | ||
| Line 100: | Line 100: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.2 | |PS conc=0.2 | ||
| Line 117: | Line 117: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=5 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.2 | |PS conc=0.2 | ||
| Line 133: | Line 133: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=5 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.2 | |PS conc=0.2 | ||
| Line 150: | Line 150: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
| Line 166: | Line 166: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=50 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
| Line 198: | Line 198: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100786 | |catalyst=Molecule:100786 | ||
|cat conc= | |cat conc=5 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
|PS conc=0.2 | |PS conc=0.2 | ||
Latest revision as of 18:59, 15 March 2025
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume [mL] | intensity [kW/m²] | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO [TOF/min] | Φ CO [%] | TON CH4 | TOF CH4 [TOF/min] | Φ CH4 [%] | TON H2 | TOF H2 [TOF/min] | Φ H2 [%] | TON HCOOH | TOF HCOOH [TOF/min] | Φ HCOOH [%] | TON MeOH | TOF MeOH [TOF/min] | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 50 | 0.2 | 0.1 |
|
|
4:1 | 460 (LED) | 3 | 1879 | 15 | 48 | 96.8%; 0%; 0.8%; 2.5%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 50 | 0.2 | 0.1 |
|
|
4:1 | Argon atmosphere | 460 (LED) | 3 | 0 | 1 | 3 | 0%; 0%; 25.0%; 75.0%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0 | 0.2 | 0.1 |
|
|
4:1 | 460 (LED) | 3 | 0 | 0 | 0 | n/a |
|
Yes | |||||||||||||||||||||||||||
| 20 | 0.2 | 0.1 |
|
|
4:1 | 460 (LED) | 3 | 2660 | 29 | 51 | 97.1%; 0%; 1.1%; 1.9%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 20 | 0.2 | 0.1 |
|
|
4:1 | Argon atmosphere | 460 (LED) | 3 | 0 | 0 | 0 | n/a |
|
Yes | ||||||||||||||||||||||||||
| 10 | 0.2 | 0.1 |
|
|
4:1 | 460 (LED) | 3 | 3087 | 121 | 35 | 95.2%; 0%; 3.7%; 1.1%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 10 | 0.2 | 0.1 |
|
|
4:1 | Argon atmosphere | 460 (LED) | 3 | 0 | 0 | 0 | n/a |
|
Yes | ||||||||||||||||||||||||||
| 5 | 0.2 | 0.1 |
|
|
4:1 | 460 (LED) | 3 | 3844 | 118 | 534 | 85.5%; 0%; 2.6%; 11.9%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 5 | 0.2 | 0.1 |
|
|
4:1 | Argon atmosphere | 460 (LED) | 3 | 0 | 1 | 0 | n/a |
|
Yes | ||||||||||||||||||||||||||
| 50 | 0.05 | 0.1 |
|
|
4:1 | 460 (LED) | 3 | 1336 | 10 | 34 | 96.8%; 0%; 0.7%; 2.5%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 50 | 0.05 | 0.1 |
|
|
4:1 | 460 (LED) | 3 | 0 | 0 | 0 | n/a |
|
Yes | |||||||||||||||||||||||||||
| 0 | 0.05 | 0.1 |
|
|
4:1 | 460 (LED) | 3 | 0 | 1 | 0 | n/a |
|
Yes | |||||||||||||||||||||||||||
| 5 | 0.2 |
|
|
|
4:1 | 460 (LED) | 3 | 160 | 8 | 22 | 84.2%; 0%; 4.2%; 11.6%; 0% |
|
Yes |
