Photocatalytic CO2 reduction with aminoanthraquinone organic dyes/Photocatalytic CO2 reduction with varying concentrations of cat and PS: Difference between revisions
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< Photocatalytic CO2 reduction with aminoanthraquinone organic dyes
investigation
Molecular process, Photocatalytic CO2 conversion experiments (Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100671 |cat conc=0.0005 |PS=Molecule:100932 |PS conc=0.0005 |e-D=Molecule:100508 |e-D conc=0.06 |solvent A=Molecule:100529 |λexc=> 400 |TON CO=3174 |include=No }}{{Photocatalytic CO2 conversion |catalyst=Molecule:100671 |cat conc=0.001 |PS=Molecule:100932 |PS conc=0.001 |e-D=Molecule:100508 |e-D conc=0.06 |solvent A=Molecule:100529 |λexc=> 400 |TON CO=3587 |inclu...") |
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|λexc=> 400 | |λexc=> 400 | ||
|TON CO=4028 | |TON CO=4028 | ||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.0005 | |||
|PS=Molecule:100932 | |||
|PS conc=0.02 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=19158 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.0006 | |||
|PS=Molecule:100932 | |||
|PS conc=0.02 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=21616 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.001 | |||
|PS=Molecule:100932 | |||
|PS conc=0.02 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=17020 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.002 | |||
|PS=Molecule:100932 | |||
|PS conc=0.02 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=11250 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.01 | |||
|PS=Molecule:100932 | |||
|PS conc=0.02 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=3942 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.02 | |||
|PS=Molecule:100932 | |||
|PS conc=0.02 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=2134 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.05 | |||
|PS=Molecule:100932 | |||
|PS conc=0.02 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=891 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.002 | |||
|PS=Molecule:100932 | |||
|PS conc=0.015 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=8772 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.002 | |||
|PS=Molecule:100932 | |||
|PS conc=0.01 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=5593 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.005 | |||
|PS=Molecule:100932 | |||
|PS conc=0.01 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=4128 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.01 | |||
|PS=Molecule:100932 | |||
|PS conc=0.01 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=4028 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.02 | |||
|PS=Molecule:100932 | |||
|PS conc=0.01 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=2325 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.002 | |||
|PS=Molecule:100932 | |||
|PS conc=0.005 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=8780 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.005 | |||
|PS=Molecule:100932 | |||
|PS conc=0.005 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=5258 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.01 | |||
|PS=Molecule:100932 | |||
|PS conc=0.005 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=2576 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100671 | |||
|cat conc=0.02 | |||
|PS=Molecule:100932 | |||
|PS conc=0.005 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.06 | |||
|solvent A=Molecule:100529 | |||
|λexc=> 400 | |||
|TON CO=1539 | |||
|include=No | |include=No | ||
}} | }} | ||
}} | }} |
Latest revision as of 10:53, 17 May 2024
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
0.0005 | 0.0005 | 0.06 |
|
|
|
> 400 | 3174 | n/a |
|
No | |||||||||||||||||||||||||||||
0.001 | 0.001 | 0.06 |
|
|
|
> 400 | 3587 | n/a |
|
No | |||||||||||||||||||||||||||||
0.002 | 0.002 | 0.06 |
|
|
|
> 400 | 3817 | n/a |
|
No | |||||||||||||||||||||||||||||
0.005 | 0.005 | 0.06 |
|
|
|
> 400 | 4978 | n/a |
|
No | |||||||||||||||||||||||||||||
0.01 | 0.01 | 0.06 |
|
|
|
> 400 | 4028 | n/a |
|
No | |||||||||||||||||||||||||||||
0.0005 | 0.02 | 0.06 |
|
|
|
> 400 | 19158 | n/a |
|
No | |||||||||||||||||||||||||||||
0.0006 | 0.02 | 0.06 |
|
|
|
> 400 | 21616 | n/a |
|
No | |||||||||||||||||||||||||||||
0.001 | 0.02 | 0.06 |
|
|
|
> 400 | 17020 | n/a |
|
No | |||||||||||||||||||||||||||||
0.002 | 0.02 | 0.06 |
|
|
|
> 400 | 11250 | n/a |
|
No | |||||||||||||||||||||||||||||
0.01 | 0.02 | 0.06 |
|
|
|
> 400 | 3942 | n/a |
|
No | |||||||||||||||||||||||||||||
0.02 | 0.02 | 0.06 |
|
|
|
> 400 | 2134 | n/a |
|
No | |||||||||||||||||||||||||||||
0.05 | 0.02 | 0.06 |
|
|
|
> 400 | 891 | n/a |
|
No | |||||||||||||||||||||||||||||
0.002 | 0.015 | 0.06 |
|
|
|
> 400 | 8772 | n/a |
|
No | |||||||||||||||||||||||||||||
0.002 | 0.01 | 0.06 |
|
|
|
> 400 | 5593 | n/a |
|
No | |||||||||||||||||||||||||||||
0.005 | 0.01 | 0.06 |
|
|
|
> 400 | 4128 | n/a |
|
No | |||||||||||||||||||||||||||||
0.01 | 0.01 | 0.06 |
|
|
|
> 400 | 4028 | n/a |
|
No | |||||||||||||||||||||||||||||
0.02 | 0.01 | 0.06 |
|
|
|
> 400 | 2325 | n/a |
|
No | |||||||||||||||||||||||||||||
0.002 | 0.005 | 0.06 |
|
|
|
> 400 | 8780 | n/a |
|
No | |||||||||||||||||||||||||||||
0.005 | 0.005 | 0.06 |
|
|
|
> 400 | 5258 | n/a |
|
No | |||||||||||||||||||||||||||||
0.01 | 0.005 | 0.06 |
|
|
|
> 400 | 2576 | n/a |
|
No | |||||||||||||||||||||||||||||
0.02 | 0.005 | 0.06 |
|
|
|
> 400 | 1539 | n/a |
|
No |