Photocatalytic Reduction of CO2 by Highly Efficient Homogeneous FeII Catalyst based on 2,6-Bis(1’,2’,3’-triazolyl-methyl)pyridine. Comparison with Analogues./Optimization of CO2 reduction conditions

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Molecule:100941	0.1	Molecule:100940	1.0	BIH	0.02			MeCN	TEOA		5:1			CO2				22	420	4	107						43									71.3%; 0%; 28.7%; 0%; 0%			No
Molecule:100941	0.1	Molecule:100940	1.0	BIH	0.02			MeCN	TEOA		5:1			CO2				22	420	20	109						54									66.9%; 0%; 33.1%; 0%; 0%			No
Molecule:100941	0.03	Molecule:100940	0.33	BIH	0.00666			MeCN	TEOA		5:1			CO2				22	420	4	238						137									63.5%; 0%; 36.5%; 0%; 0%			No
Molecule:100941	0.03	Molecule:100940	1.0	BIH	0.02			MeCN	TEOA		5:1			CO2				22	420	4	314						151									67.5%; 0%; 32.5%; 0%; 0%			No
Molecule:100941	0.01	Molecule:100940	1.0	BIH	0.02			MeCN	TEOA		5:1			CO2				22	420	4	576						287									66.7%; 0%; 33.3%; 0%; 0%			Yes
Molecule:100941	0.01	Molecule:100940	1.0	BIH	0.1			MeCN	TEOA		5:1			CO2				22	420	4	80						33									70.8%; 0%; 29.2%; 0%; 0%			Yes
Molecule:100941	0.1	Molecule:100940	1.0	BIH	0.1			MeCN	TEOA		5:1			CO2				22	420	4	80						33									70.8%; 0%; 29.2%; 0%; 0%			Yes