Photocatalytic CO2 Reduction Mediated by Electron Transfer via the Excited Triplet State of Zn(II) Porphyrin/photocatalytic CO2 conversion: Difference between revisions

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< Photocatalytic CO2 Reduction Mediated by Electron Transfer via the Excited Triplet State of Zn(II) Porphyrin
investigation
Molecular process, Photocatalytic CO2 conversion experiments
(Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100954 |cat conc=0.05 |e-D=Molecule:100508 |e-D conc=0.05 |solvent A=Molecule:100531 |additives=phenol |additives conc=0.1 |feedstock gas=CO2 |λexc=420 nm |Φ CO=8 |include=No }} }}")
 
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|feedstock gas=CO2
|feedstock gas=CO2
|λexc=420 nm
|λexc=420 nm
|Φ CO=8
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100954
|cat conc=0.05
|e-D=Molecule:100508
|e-D conc=0.05
|solvent A=Molecule:100531
|additives=phenol
|additives conc=0.1
|feedstock gas=CO2
|λexc=560 nm
|Φ CO=8
|Φ CO=8
|include=No
|include=No
}}
}}
}}
}}

Revision as of 09:51, 16 May 2024

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

(Zn(tBuPP))-(Re(Phen)Br(CO)3)

0.05


BIH

0.05


DMA



phenol 0.1 CO2 420 nm 8 n/a

8

No

(Zn(tBuPP))-(Re(Phen)Br(CO)3)

0.05


BIH

0.05


DMA



phenol 0.1 CO2 560 nm 8 n/a

8

No