Photocatalytic Reduction of CO2 by Highly Efficient Homogeneous FeII Catalyst based on 2,6-Bis(1’,2’,3’-triazolyl-methyl)pyridine. Comparison with Analogues./Optimization of CO2 reduction conditions: Difference between revisions

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(Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100941 |cat conc=0.1 |PS=Molecule:100940 |PS conc=1.0 |e-D=Molecule:100508 |e-D conc=0.02 |solvent A=Molecule:100530 |solvent B=Molecule:100507 |feedstock gas=CO2 |irr time=4 |TON CO=107 |include=No }} }}")
 
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|solvent B=Molecule:100507
|solvent B=Molecule:100507
|feedstock gas=CO2
|feedstock gas=CO2
|Temperature=22
|λexc=420
|irr time=4
|irr time=4
|TON CO=107
|TON CO=107

Revision as of 12:20, 16 May 2024

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100941

0.1

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


CO2 22 420 4 107 n/a


No