Photocatalytic Reduction of CO2 by Highly Efficient Homogeneous FeII Catalyst based on 2,6-Bis(1’,2’,3’-triazolyl-methyl)pyridine. Comparison with Analogues./Optimization of CO2 reduction conditions: Difference between revisions
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< Photocatalytic Reduction of CO2 by Highly Efficient Homogeneous FeII Catalyst based on 2,6-Bis(1’,2’,3’-triazolyl-methyl)pyridine. Comparison with Analogues.
investigation
Molecular process, Photocatalytic CO2 conversion experiments (Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100941 |cat conc=0.1 |PS=Molecule:100940 |PS conc=1.0 |e-D=Molecule:100508 |e-D conc=0.02 |solvent A=Molecule:100530 |solvent B=Molecule:100507 |feedstock gas=CO2 |irr time=4 |TON CO=107 |include=No }} }}") |
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|solvent B=Molecule:100507 | |solvent B=Molecule:100507 | ||
|feedstock gas=CO2 | |feedstock gas=CO2 | ||
|Temperature=22 | |||
|λexc=420 | |||
|irr time=4 | |irr time=4 | ||
|TON CO=107 | |TON CO=107 |
Revision as of 12:20, 16 May 2024
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
0.1 | 1.0 | 0.02 |
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CO2 | 22 | 420 | 4 | 107 | n/a |
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No |