Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst/Photocatalytic reduction of CO2

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1			DMF						CO2					> 435	47	50			8			8									75.8%; 12.1%; 12.1%; 0%; 0%			Yes
Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1			DMF				TFE	0.1	CO2					> 435	47	71			14			10									74.7%; 14.7%; 10.5%; 0%; 0%			Yes
Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1			DMF				TFE	0.1	CO2					> 435	102	140			29			23									72.9%; 15.1%; 12.0%; 0%; 0%			Yes