Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore/Photocatalytic CO2 reduction: best results

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Fe(DHPP)Cl	0.0002	purpurin	0.1	BIH	0.01			DMF											>400	7	88	45	100				0									n/a	100		Yes
Fe(DHPP)Cl	0.0002	[Cu(PP)2][TBA]2	0.1	BIH	0.01			DMF											>400	7	4779	1356					270									94.7%; 0%; 5.3%; 0%; 0%			Yes
Fe(DHPP)Cl	0.0002	[Cu(PP)2][TBA]2	0.1	BIH	0.1			DMF											>400	23	16109	7650					843									95.0%; 0%; 5.0%; 0%; 0%			Yes
Fe(DHPP)Cl	0	[Cu(PP)2][TBA]2	0.1	BIH	0.1			DMF											>400	1	4.4	4.3														n/a			Yes