Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes/Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2: Difference between revisions

Latest revision as of 15:38, 17 May 2024

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	additives	λexc [nm]	t [h]	TON CO	TON H2	TON HCOOH	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	include
[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	2660	23	35	97.9%; 0%; 0.8%; 1.3%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	0	2	1	0%; 0%; 66.7%; 33.3%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN	Argon atmosphere	460 (LED)	1.33	0	33	0	n/a	Yes
[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1			MeCN		460 (LED)	1.33	182	0	11	94.3%; 0%; 0%; 5.7%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3			TEOA	0.5	MeCN		460 (LED)	1.33	114	25	25	69.5%; 0%; 15.2%; 15.2%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0.01	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	1875	11	18	98.5%; 0%; 0.6%; 0.9%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0.2	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	1262	7	23	97.7%; 0%; 0.5%; 1.8%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	497	5	3	98.4%; 0%; 1.0%; 0.6%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.3			TEOA	0.5	MeCN		460 (LED)	1.33	0	1	1	0%; 0%; 50.0%; 50.0%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0.1	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	466	2	22	95.1%; 0%; 0.4%; 4.5%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.5	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	521	49	6	90.5%; 0%; 8.5%; 1.0%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.5	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	136	43	5	73.9%; 0%; 23.4%; 2.7%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	366	15	4	95.1%; 0%; 3.9%; 1.0%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1	TEOA	0.5	MeCN	Argon atmosphere	460 (LED)	1.33	0	3	1	0%; 0%; 75.0%; 25.0%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.2	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	0	6	1	0%; 0%; 85.7%; 14.3%; 0%	Yes
Co(ClO4)2	0.05	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	33	11	1	73.3%; 0%; 24.4%; 2.2%; 0%	Yes
[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.3			TEOA	0.5	MeCN		460 (LED)	1.33	0	1	1	0%; 0%; 50.0%; 50.0%; 0%	Yes

@@ Line 13: / Line 13: @@
 |irr time=1.33
 |TON CO=2660
-|Φ CO=98
 |TON H2=23
-|Φ H2=1
 |TON HCOOH=35
-|Φ HCOOH=1
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 32: / Line 29: @@
 |irr time=1.33
 |TON CO=0
-|Φ CO=0
 |TON H2=2
-|Φ H2=67
 |TON HCOOH=1
-|Φ HCOOH=33
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 52: / Line 46: @@
 |irr time=1.33
 |TON CO=0
-|Φ CO=0
 |TON H2=33
-|Φ H2=100
 |TON HCOOH=0
-|Φ HCOOH=0
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 69: / Line 60: @@
 |irr time=1.33
 |TON CO=182
-|Φ CO=94
 |TON H2=0
-|Φ H2=0
 |TON HCOOH=11
-|Φ HCOOH=6
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 86: / Line 74: @@
 |irr time=1.33
 |TON CO=114
-|Φ CO=70
 |TON H2=25
-|Φ H2=15
 |TON HCOOH=25
-|Φ HCOOH=15
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 105: / Line 90: @@
 |irr time=1.33
 |TON CO=1875
-|Φ CO=98
 |TON H2=11
-|Φ H2=1
 |TON HCOOH=18
-|Φ HCOOH=1
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 124: / Line 106: @@
 |irr time=1.33
 |TON CO=1262
-|Φ CO=98
 |TON H2=7
-|Φ H2=0
 |TON HCOOH=23
-|Φ HCOOH=2
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 143: / Line 122: @@
 |irr time=1.33
 |TON CO=497
-|Φ CO=98
 |TON H2=5
-|Φ H2=1
 |TON HCOOH=3
-|Φ HCOOH=1
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 160: / Line 136: @@
 |irr time=1.33
 |TON CO=0
-|Φ CO=0
 |TON H2=1
-|Φ H2=50
 |TON HCOOH=1
-|Φ HCOOH=50
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 179: / Line 152: @@
 |irr time=1.33
 |TON CO=466
-|Φ CO=95
 |TON H2=2
-|Φ H2=0
 |TON HCOOH=22
-|Φ HCOOH=5
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 198: / Line 168: @@
 |irr time=1.33
 |TON CO=521
-|Φ CO=90
 |TON H2=49
-|Φ H2=9
 |TON HCOOH=6
-|Φ HCOOH=1
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 217: / Line 184: @@
 |irr time=1.33
 |TON CO=136
-|Φ CO=74
 |TON H2=43
-|Φ H2=23
 |TON HCOOH=5
-|Φ HCOOH=3
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 236: / Line 200: @@
 |irr time=1.33
 |TON CO=366
-|Φ CO=95
 |TON H2=15
-|Φ H2=4
 |TON HCOOH=4
-|Φ HCOOH=1
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 256: / Line 217: @@
 |irr time=1.33
 |TON CO=0
-|Φ CO=0
 |TON H2=3
-|Φ H2=75
 |TON HCOOH=1
-|Φ HCOOH=25
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 275: / Line 233: @@
 |irr time=1.33
 |TON CO=0
-|Φ CO=0
 |TON H2=6
-|Φ H2=86
 |TON HCOOH=1
-|Φ HCOOH=14
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 294: / Line 249: @@
 |irr time=1.33
 |TON CO=33
-|Φ CO=65
 |TON H2=11
-|Φ H2=21
 |TON HCOOH=1
-|Φ HCOOH=14
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 311: / Line 263: @@
 |irr time=1.33
 |TON CO=0
-|Φ CO=0
 |TON H2=1
-|Φ H2=50
 |TON HCOOH=1
-|Φ HCOOH=50
 |include=Yes
 }}
 }}

Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes/Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2: Difference between revisions

Latest revision as of 15:38, 17 May 2024

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