An integrated Re(I) photocatalyst and sensitizer that activates the formation of formic acid from reduction of CO2/Effect of proton donor: Difference between revisions
From ChemWiki
< An integrated Re(I) photocatalyst and sensitizer that activates the formation of formic acid from reduction of CO2
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
No edit summary |
No edit summary |
||
| Line 12: | Line 12: | ||
|TON H2=4.25 | |TON H2=4.25 | ||
|TON HCOOH=25 | |TON HCOOH=25 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 26: | Line 25: | ||
|TON H2=5.75 | |TON H2=5.75 | ||
|TON HCOOH=25.75 | |TON HCOOH=25.75 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 40: | Line 38: | ||
|TON H2=5.25 | |TON H2=5.25 | ||
|TON HCOOH=27 | |TON HCOOH=27 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 54: | Line 51: | ||
|TON H2=5.75 | |TON H2=5.75 | ||
|TON HCOOH=19 | |TON HCOOH=19 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 68: | Line 64: | ||
|TON H2=2 | |TON H2=2 | ||
|TON HCOOH=12.5 | |TON HCOOH=12.5 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 82: | Line 77: | ||
|TON H2=2.75 | |TON H2=2.75 | ||
|TON HCOOH=14.5 | |TON HCOOH=14.5 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 96: | Line 90: | ||
|TON H2=1 | |TON H2=1 | ||
|TON HCOOH=10.25 | |TON HCOOH=10.25 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 110: | Line 103: | ||
|TON H2=16.25 | |TON H2=16.25 | ||
|TON HCOOH=11.25 | |TON HCOOH=11.25 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 124: | Line 116: | ||
|TON H2=3.25 | |TON H2=3.25 | ||
|TON HCOOH=20.5 | |TON HCOOH=20.5 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 138: | Line 129: | ||
|TON H2=3.5 | |TON H2=3.5 | ||
|TON HCOOH=24 | |TON HCOOH=24 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 152: | Line 142: | ||
|TON H2=7.75 | |TON H2=7.75 | ||
|TON HCOOH=30 | |TON HCOOH=30 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 166: | Line 155: | ||
|TON H2=9 | |TON H2=9 | ||
|TON HCOOH=34.75 | |TON HCOOH=34.75 | ||
|include=No | |include=No | ||
}} | }} | ||
}} | }} | ||
Latest revision as of 15:32, 17 May 2024
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
|
|
4:1 | water | 405 nm | 24 | 4.25 | 25 | 0%; 0%; 14.5%; 85.5%; 0% |
|
No | |||||||||||||||||||||||||||||
|
|
|
4:1 | water | 405 nm | 24 | 5.75 | 25.75 | 0%; 0%; 18.3%; 81.7%; 0% |
|
No | |||||||||||||||||||||||||||||
|
|
|
4:1 | phenol | 405 nm | 24 | 5.25 | 27 | 0%; 0%; 16.3%; 83.7%; 0% |
|
No | |||||||||||||||||||||||||||||
|
|
|
4:1 | phenol | 405 nm | 24 | 5.75 | 19 | 0%; 0%; 23.2%; 76.8%; 0% |
|
No | |||||||||||||||||||||||||||||
|
|
|
4:1 | water | 405 nm | 24 | 2 | 12.5 | 0%; 0%; 13.8%; 86.2%; 0% |
|
No | |||||||||||||||||||||||||||||
|
|
|
4:1 | water | 405 nm | 24 | 2.75 | 14.5 | 0%; 0%; 15.9%; 84.1%; 0% |
|
No | |||||||||||||||||||||||||||||
|
|
|
4:1 | phenol | 405 nm | 24 | 1 | 10.25 | 0%; 0%; 8.9%; 91.1%; 0% |
|
No | |||||||||||||||||||||||||||||
|
|
|
4:1 | phenol | 405 nm | 24 | 16.25 | 11.25 | 0%; 0%; 59.1%; 40.9%; 0% |
|
No | |||||||||||||||||||||||||||||
|
|
|
4:1 | water | 405 nm | 24 | 3.25 | 20.5 | 0%; 0%; 13.7%; 86.3%; 0% |
|
No | |||||||||||||||||||||||||||||
|
|
|
4:1 | water | 405 nm | 24 | 3.5 | 24 | 0%; 0%; 12.7%; 87.3%; 0% |
|
No | |||||||||||||||||||||||||||||
|
|
|
4:1 | phenol | 405 nm | 24 | 7.75 | 30 | 0%; 0%; 20.5%; 79.5%; 0% |
|
No | |||||||||||||||||||||||||||||
|
|
|
4:1 | phenol | 405 nm | 24 | 9 | 34.75 | 0%; 0%; 20.6%; 79.4%; 0% |
|
No |
