A Dinuclear Cobalt Cryptate as a Homogeneous Photocatalyst for Highly Selective and Efficient Visible-Light Driven CO2 Reduction to CO in CH3CN-H2O Solution/Best result and control experiments

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Molecule:100776	0.000025	[Ru(phen)3][PF6]2	0.4	TEOA	300			MeCN	H2O		4:1							25	450 nm (LED, 100 mW.cm^-2)	10	16896	0.47	98				368	0.01	2							97.9%; 0%; 2.1%; 0%; 0%	100		Yes
Molecule:100776	0.0005	[Ru(phen)3][PF6]2	0.4	TEOA	300			MeCN	H2O		4:1	CO2/Ar (10:90) atmosphere						25	450 nm (LED, 100 mW.cm^-2)	10	684	0.019	92				56	0.0016	8							92.4%; 0%; 7.6%; 0%; 0%	100		No
		[Ru(phen)3][PF6]2	0.4	TEOA	300			MeCN	H2O		4:1							25	450 nm (LED, 100 mW.cm^-2)	10																n/a			Yes
Molecule:100776	0.000025			TEOA	300			MeCN	H2O		4:1							25	450 nm (LED, 100 mW.cm^-2)	10																n/a			Yes
Molecule:100776	0.000025	[Ru(phen)3][PF6]2	0.4					MeCN	H2O		4:1							25	450 nm (LED, 100 mW.cm^-2)	10																n/a			Yes
Molecule:100776	0.000025	[Ru(phen)3][PF6]2	0.4	TEOA	300			MeCN	H2O		4:1							25		10																n/a			Yes
Molecule:100776	0.000025	[Ru(phen)3][PF6]2	0.4	TEOA	300			MeCN	H2O		4:1	Argon atmosphere						25	450 nm (LED, 100 mW.cm^-2)	10																n/a			Yes