Photocatalytic CO2 reduction using a Mn complex as a catalyst/Photocatalytic CO2 reduction: conditions optimization

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume [mL]	intensity [kW/m²]	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON CH4	TOF CH4 [TOF/min]	Φ CH4 [%]	TON H2	TOF H2 [TOF/min]	Φ H2 [%]	TON HCOOH	TOF HCOOH [TOF/min]	Φ HCOOH [%]	TON MeOH	TOF MeOH [TOF/min]	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Mn(bpy)(CO)3Br	0.05	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1			DMF	TEOA		4:1								480	0.17																n/a			No
Mn(bpy)(CO)3Br	0.05	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1			DMF	TEOA		4:1								480	2																n/a			Yes
Mn(bpy)(CO)3Br	0.05	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1			DMF	TEOA		4:1								480	12																n/a			Yes
Mn(bpy)(CO)3Br	0.05	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1			DMF	TEOA		4:1	Argon gas							480	12																n/a			Yes
		[Ru(dmb)3][PF6]2	0.05	BNAH	0.1			DMF	TEOA		4:1								480	2																n/a			Yes
		[Ru(dmb)3][PF6]2	0.05	BNAH	0.1			DMF	TEOA		4:1								480	12																n/a			Yes
Mn(bpy)(CO)3Br	0.05			BNAH	0.1			DMF	TEOA		4:1								480	12																n/a			No
Mn(bpy)(CO)3Br	0.05	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1			DMA	TEOA		4:1								480	720																n/a			Yes
		[Ru(dmb)3][PF6]2	0.05	BNAH	0.1			DMA	TEOA		4:1								480	12																n/a			Yes
Mn(bpy)(CO)3Br	0.05	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1			MeCN	TEOA		4:1								480	12																n/a			Yes
		[Ru(dmb)3][PF6]2	0.05	BNAH	0.1			MeCN	TEOA		4:1								480	12																n/a			Yes
Mn(bpy)(CO)3Br	0.05	Ru(bpy)3	0.05	BNAH	0.1			DMF	TEOA		4:1								480	12																n/a			Yes