Light-Driven Reduction of CO2 to CO in Water with a Cobalt Molecular Catalyst and an Organic Sensitizer/Photocatalytic CO2 Reduction by 1 (2 μM) in CO2-Saturated Aqueous CH3CN Solutions: Difference between revisions

Latest revision as of 13:33, 29 January 2026

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solv A/B/C	additives	λexc [nm]	TON CO	TON H2	TON HCOOH	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	include
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	100/0		450	2332	106	1370	61.2%; 0%; 2.8%; 36.0%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	95/5		450	6228	304	2441	69.4%; 0%; 3.4%; 27.2%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	90/10		450	14691	283	1097	91.4%; 0%; 1.8%; 6.8%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	85/15		450	15822	220	1147	92.0%; 0%; 1.3%; 6.7%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	80/20		450	18989	227	1215	92.9%; 0%; 1.1%; 5.9%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O	80/20	Hg	450	19646	226	415	96.8%; 0%; 1.1%; 2.0%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O	100/0		450	183	9	419	30.0%; 0%; 1.5%; 68.6%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O	95/5		450	612	202	51	70.8%; 0%; 23.4%; 5.9%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O	90/10		450	515	253	46	63.3%; 0%; 31.1%; 5.7%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O	85/15		450	3171	498	179	82.4%; 0%; 12.9%; 4.7%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O	80/20		450	6331	264	179	93.5%; 0%; 3.9%; 2.6%; 0%	No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O	80/20	Hg	450	6286	304	97	94.0%; 0%; 4.5%; 1.5%; 0%	No

@@ Line 13: / Line 13: @@
 |solvent-ratio=100/0
 |λexc=450
-|TON CO=2332
+|Turnover_number__CO=2332
-|TON H2=106
+|Turnover_number__H2=106
-|TON HCOOH=1370
+|Turnover_number__HCOOH=1370
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 30: / Line 30: @@
 |solvent-ratio=95/5
 |λexc=450
-|TON CO=6228
+|Turnover_number__CO=6228
-|TON H2=304
+|Turnover_number__H2=304
-|TON HCOOH=2441
+|Turnover_number__HCOOH=2441
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 47: / Line 47: @@
 |solvent-ratio=90/10
 |λexc=450
-|TON CO=14691
+|Turnover_number__CO=14691
-|TON H2=283
+|Turnover_number__H2=283
-|TON HCOOH=1097
+|Turnover_number__HCOOH=1097
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 64: / Line 64: @@
 |solvent-ratio=85/15
 |λexc=450
-|TON CO=15822
+|Turnover_number__CO=15822
-|TON H2=220
+|Turnover_number__H2=220
-|TON HCOOH=1147
+|Turnover_number__HCOOH=1147
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 81: / Line 81: @@
 |solvent-ratio=80/20
 |λexc=450
-|TON CO=18989
+|Turnover_number__CO=18989
-|TON H2=227
+|Turnover_number__H2=227
-|TON HCOOH=1215
+|Turnover_number__HCOOH=1215
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 99: / Line 99: @@
 |additives=Hg
 |λexc=450
-|TON CO=19646
+|Turnover_number__CO=19646
-|TON H2=226
+|Turnover_number__H2=226
-|TON HCOOH=415
+|Turnover_number__HCOOH=415
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 116: / Line 116: @@
 |solvent-ratio=100/0
 |λexc=450
-|TON CO=183
+|Turnover_number__CO=183
-|TON H2=9
+|Turnover_number__H2=9
-|TON HCOOH=419
+|Turnover_number__HCOOH=419
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 133: / Line 133: @@
 |solvent-ratio=95/5
 |λexc=450
-|TON CO=612
+|Turnover_number__CO=612
-|TON H2=202
+|Turnover_number__H2=202
-|TON HCOOH=51
+|Turnover_number__HCOOH=51
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 150: / Line 150: @@
 |solvent-ratio=90/10
 |λexc=450
-|TON CO=515
+|Turnover_number__CO=515
-|TON H2=253
+|Turnover_number__H2=253
-|TON HCOOH=46
+|Turnover_number__HCOOH=46
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 167: / Line 167: @@
 |solvent-ratio=85/15
 |λexc=450
-|TON CO=3171
+|Turnover_number__CO=3171
-|TON H2=498
+|Turnover_number__H2=498
-|TON HCOOH=179
+|Turnover_number__HCOOH=179
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 184: / Line 184: @@
 |solvent-ratio=80/20
 |λexc=450
-|TON CO=6331
+|Turnover_number__CO=6331
-|TON H2=264
+|Turnover_number__H2=264
-|TON HCOOH=179
+|Turnover_number__HCOOH=179
 |include=No
 }}{{Photocatalytic CO2 conversion
@@ Line 202: / Line 202: @@
 |additives=Hg
 |λexc=450
-|TON CO=6286
+|Turnover_number__CO=6286
-|TON H2=304
+|Turnover_number__H2=304
-|TON HCOOH=97
+|Turnover_number__HCOOH=97
 |include=No
 }}
 }}

Light-Driven Reduction of CO2 to CO in Water with a Cobalt Molecular Catalyst and an Organic Sensitizer/Photocatalytic CO2 Reduction by 1 (2 μM) in CO2-Saturated Aqueous CH3CN Solutions: Difference between revisions

Latest revision as of 13:33, 29 January 2026

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