Light-Driven Reduction of CO2 to CO in Water with a Cobalt Molecular Catalyst and an Organic Sensitizer/Photocatalytic CO2 Reduction by 1 (2 μM) in CO2-Saturated Aqueous CH3CN Solutions: Difference between revisions
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< Light-Driven Reduction of CO2 to CO in Water with a Cobalt Molecular Catalyst and an Organic Sensitizer
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
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| Line 170: | Line 170: | ||
|TON H2=498 | |TON H2=498 | ||
|TON HCOOH=179 | |TON HCOOH=179 | ||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100788 | |||
|cat conc=0.002 | |||
|PS=Molecule:100797 | |||
|PS conc=0.2 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.1 | |||
|H-D=Molecule:100505 | |||
|H-D conc=0.15 | |||
|solvent A=Molecule:100530 | |||
|solvent B=Molecule:100616 | |||
|solvent-ratio=80/20 | |||
|λexc=450 | |||
|TON CO=6331 | |||
|TON H2=264 | |||
|TON HCOOH=179 | |||
|include=No | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100788 | |||
|cat conc=0.002 | |||
|PS=Molecule:100797 | |||
|PS conc=0.2 | |||
|e-D=Molecule:100508 | |||
|e-D conc=0.1 | |||
|H-D=Molecule:100505 | |||
|H-D conc=0.15 | |||
|solvent A=Molecule:100530 | |||
|solvent B=Molecule:100616 | |||
|solvent-ratio=80/20 | |||
|additives=Hg | |||
|λexc=450 | |||
|TON CO=6286 | |||
|TON H2=304 | |||
|TON HCOOH=97 | |||
|include=No | |include=No | ||
}} | }} | ||
}} | }} | ||
Latest revision as of 14:15, 17 November 2023
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.002 | 0.2 | 0.1 | 0.15 |
|
100/0 | 450 | 2332 | 106 | 1370 | 61.2%; 0%; 2.8%; 36.0%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.002 | 0.2 | 0.1 | 0.15 |
|
95/5 | 450 | 6228 | 304 | 2441 | 69.4%; 0%; 3.4%; 27.2%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.002 | 0.2 | 0.1 | 0.15 |
|
90/10 | 450 | 14691 | 283 | 1097 | 91.4%; 0%; 1.8%; 6.8%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.002 | 0.2 | 0.1 | 0.15 |
|
85/15 | 450 | 15822 | 220 | 1147 | 92.0%; 0%; 1.3%; 6.7%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.002 | 0.2 | 0.1 | 0.15 |
|
80/20 | 450 | 18989 | 227 | 1215 | 92.9%; 0%; 1.1%; 5.9%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.002 | 0.2 | 0.1 | 0.15 |
|
80/20 | Hg | 450 | 19646 | 226 | 415 | 96.8%; 0%; 1.1%; 2.0%; 0% |
|
No | ||||||||||||||||||||||||||
| 0.002 | 0.2 | 0.1 | 0.15 |
|
100/0 | 450 | 183 | 9 | 419 | 30.0%; 0%; 1.5%; 68.6%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.002 | 0.2 | 0.1 | 0.15 |
|
95/5 | 450 | 612 | 202 | 51 | 70.8%; 0%; 23.4%; 5.9%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.002 | 0.2 | 0.1 | 0.15 |
|
90/10 | 450 | 515 | 253 | 46 | 63.3%; 0%; 31.1%; 5.7%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.002 | 0.2 | 0.1 | 0.15 |
|
85/15 | 450 | 3171 | 498 | 179 | 82.4%; 0%; 12.9%; 4.7%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.002 | 0.2 | 0.1 | 0.15 |
|
80/20 | 450 | 6331 | 264 | 179 | 93.5%; 0%; 3.9%; 2.6%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.002 | 0.2 | 0.1 | 0.15 |
|
80/20 | Hg | 450 | 6286 | 304 | 97 | 94.0%; 0%; 4.5%; 1.5%; 0% |
|
No |
