Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes/Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2: Difference between revisions

Revision as of 12:10, 11 August 2023

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	additives	λexc [nm]	t [h]	TON CO	Φ CO [%]	TON H2	Φ H2 [%]	TON HCOOH	Φ HCOOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	include
[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	2660	98	23	1	35	1	97.9%; 0%; 0.8%; 1.3%; 0%	100	No
[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN		460 (LED)	1.33	0	0	2	67	1	33	0%; 0%; 66.7%; 33.3%; 0%	100	No
[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1	TEOA	0.5	MeCN	Argon atmosphere	460 (LED)	1.33	0	0	33	100	0	0	n/a	100	No

@@ Line 18: / Line 18: @@
 |TON HCOOH=35
 |Φ HCOOH=1
+|include=No
+}}{{Photocatalytic CO2 conversion
+|catalyst=Molecule:100788
+|cat conc=0
+|PS=Molecule:100787
+|PS conc=0.3
+|e-D=Molecule:100508
+|e-D conc=0.1
+|H-D=Molecule:100507
+|H-D conc=0.5
+|solvent A=Molecule:100530
+|λexc=460 (LED)
+|irr time=1.33
+|TON CO=0
+|Φ CO=0
+|TON H2=2
+|Φ H2=67
+|TON HCOOH=1
+|Φ HCOOH=33
+|include=No
+}}{{Photocatalytic CO2 conversion
+|catalyst=Molecule:100788
+|cat conc=0.005
+|PS=Molecule:100787
+|PS conc=0.3
+|e-D=Molecule:100508
+|e-D conc=0.1
+|H-D=Molecule:100507
+|H-D conc=0.5
+|solvent A=Molecule:100530
+|additives=Argon atmosphere
+|λexc=460 (LED)
+|irr time=1.33
+|TON CO=0
+|Φ CO=0
+|TON H2=33
+|Φ H2=100
+|TON HCOOH=0
+|Φ HCOOH=0
 |include=No
 }}
 }}